非离子表面活性化合物。十、溶剂对胶束性质的影响

Paul Becher
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引用次数: 55

摘要

报道了聚氧乙烯(23)十二烷基醇在乙醇-水和二氧六烷-水溶剂体系中的临界胶束浓度和胶束分子量的测量。随着添加剂浓度的增加,cmc增大,胶束重量减小;当浓度超过25%时,不会形成胶束。用胶束化所需的自由能对结果作了定性解释。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Nonionic surface-active compounds. X. Effect of solvent on micellar properties

Measurements of the critical micelle concentration and of micellar molecular weight are reported for polyoxyethylene (23) lauryl alcohol in ethanol-water and dioxane-water solvent systems. With increasing concentration of additive, the c.m.c. increases and the micellar weight decreases; at concentrations above about 25%, no micelle formation occurs. The results are explained qualitatively in terms of the free energy requirements for micellization.

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