水分子的新自旋异构体

V. K. Konyukhov
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引用次数: 1

摘要

提出了水分子与固体表面相互作用的新模型,其中分子获得了新的物理性质,其结果可以看到,例如蒸汽压比原来的值下降了1/3。水分子失去了三个平移自由度中的两个,它也失去了完整的旋转光谱但得到了混合自旋态而不是由分子内的两个质子提供的纯粹的原始自旋态。考虑到分子性质的显著变化,可以断言新的自旋异构体可能存在于一定的环境条件下。将该模型的预测结果与两种吸附模型的实验数据进行了比较,其中一种模型对应于分子保持在表面的常规情况,另一种模型对应于分子存在于气体中的情况。实验数据的两种解释形式都得到了很好的结果。Hopf图和几何代数的数学结构在分子模型的创建过程中被使用。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
New Spin Isomers of Water Molecule
It is proposed the new model of interplay of water molecule with solid surface, where molecules get new physical properties the result of which one can see, for example, in the fall of vapor pressure of 1/3 compared to its original value. The water molecule loses two of three translation degrees of freedom, it loses also the full rotational spectrum but obtains mixed spin states instead of the pure original spin state which is provided by two protons inside the molecule. By taking into account the significant change in properties of molecules one can assert that the new spin isomers may exist under the certain environmental conditions. The predictions of the model are compared with experimental data within two adsorption models, one of which corresponds to the conventional case which suggests of keeping molecules on surface, and another case where molecules are found in gas. Two forms of the interpretation of experimental data give good results. The mathematical constructions of the Hopf map and of the geometric algebras are used during the creation of molecular models.
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