{"title":"含s-席夫碱二有机锡配合物的电子冲击破碎研究","authors":"A.K. Saxena, J.K. Koacher, J.P. Tandon ∗","doi":"10.1016/0020-1650(81)80007-4","DOIUrl":null,"url":null,"abstract":"<div><p>Complexes of the type Bu<sub>2</sub>SnL (where L is the anion having donor system <span><math><mtext>ON</mtext></math></span><span><math><mtext>NS</mtext></math></span> such as Salicylaldehyde Thiosemicarbazone or salicylaldehyde-S-Benzyl dithio carbazate) have been synthesized. Fragmentation schemes upon electron impact have been constructed on the basis of measurements of metastable transitions and the isotopic contributions for the fragment ions containing the Sn atoms.</p></div>","PeriodicalId":13630,"journal":{"name":"Inorganic and Nuclear Chemistry Letters","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"1981-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0020-1650(81)80007-4","citationCount":"26","resultStr":"{\"title\":\"Electron impact induced fragmentation studies on some diorganotin complexes of s-containing schiff bases\",\"authors\":\"A.K. Saxena, J.K. Koacher, J.P. Tandon ∗\",\"doi\":\"10.1016/0020-1650(81)80007-4\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Complexes of the type Bu<sub>2</sub>SnL (where L is the anion having donor system <span><math><mtext>ON</mtext></math></span><span><math><mtext>NS</mtext></math></span> such as Salicylaldehyde Thiosemicarbazone or salicylaldehyde-S-Benzyl dithio carbazate) have been synthesized. Fragmentation schemes upon electron impact have been constructed on the basis of measurements of metastable transitions and the isotopic contributions for the fragment ions containing the Sn atoms.</p></div>\",\"PeriodicalId\":13630,\"journal\":{\"name\":\"Inorganic and Nuclear Chemistry Letters\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1981-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/0020-1650(81)80007-4\",\"citationCount\":\"26\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Inorganic and Nuclear Chemistry Letters\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/0020165081800074\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Inorganic and Nuclear Chemistry Letters","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0020165081800074","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 26
摘要
已经合成了Bu2SnL型配合物(其中L是具有供体系统ONNS的阴离子,如水杨醛硫代氨基脲或水杨醛- s -苄基双硫代氨基甲酸酯)。基于亚稳跃迁的测量和含有锡原子的碎片离子的同位素贡献,构建了电子碰撞的碎片方案。
Electron impact induced fragmentation studies on some diorganotin complexes of s-containing schiff bases
Complexes of the type Bu2SnL (where L is the anion having donor system such as Salicylaldehyde Thiosemicarbazone or salicylaldehyde-S-Benzyl dithio carbazate) have been synthesized. Fragmentation schemes upon electron impact have been constructed on the basis of measurements of metastable transitions and the isotopic contributions for the fragment ions containing the Sn atoms.