萘普生锂盐的合成、热及光谱研究。

D. Gálico, C. V. Nova, R. B. Guerra, G. Bannach
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引用次数: 1

摘要

合成了一种新型锂盐并对其进行了表征。盐的化学计量量为LiNap。在空气和氮气环境中,盐分别在260℃和275℃前热稳定,直到分解后才融化。盐是高度结晶的,晶体呈棱柱状。对该化合物进行了紫外、可见、近红外和MIR光谱研究。荧光研究表明,当在236或264 nm激发时,盐在356nm内发光。这种发射被分配到化合物的第一单线态激发态到单线态基态。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
SYNTHESIS, THERMAL AND SPECTROSCOPIC STUDIES OF LITHIUM SALT OF NAPROXEN.
A new lithium salt was synthesized and characterized. The stoichiometry of the salt was LiNap . 1H 2 O. The salt was thermally stable until 260 °C and 275 °C in air and nitrogen atmospheres, respectively, and don’t melt until the decomposition. The salt was highly crystalline and the crystal has a prismatic form. A spectroscopic study of the compound was done covering the UV, Vis, NIR and MIR regions. The fluorescence studies shown that the salt emits in 356 nm when excited on 236 or 264 nm. This emission was assigned to the first singlet excited state to the singlet ground level state of the compound.
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