{"title":"nichtebenen处境deformationsschwingungν2相对国情咨文totalsymmetrischen valenzsehwingungν1在trithiocarbonaten","authors":"A. Müller, B. Krebs","doi":"10.1016/0371-1951(66)80152-2","DOIUrl":null,"url":null,"abstract":"<div><p>The frequency ratio of the ν<sub>1</sub>(<em>A</em><sub>1</sub>′) and ν<sub>t2</sub>(<em>E′</em>) vibrations of the CS<sub>3</sub><sup>2−</sup> ion in trithiocarbonates was observed to assume values below as well as above unity, depending on the crystal field and, probably, on bond interactions between metal and sulfur.</p></div>","PeriodicalId":101180,"journal":{"name":"Spectrochimica Acta","volume":"22 8","pages":"Pages 1535-1536"},"PeriodicalIF":0.0000,"publicationDate":"1966-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0371-1951(66)80152-2","citationCount":"5","resultStr":"{\"title\":\"Die lage der nichtebenen deformationsschwingung ν2 relativ zur lage der totalsymmetrischen valenzsehwingung ν1 in trithiocarbonaten\",\"authors\":\"A. Müller, B. Krebs\",\"doi\":\"10.1016/0371-1951(66)80152-2\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The frequency ratio of the ν<sub>1</sub>(<em>A</em><sub>1</sub>′) and ν<sub>t2</sub>(<em>E′</em>) vibrations of the CS<sub>3</sub><sup>2−</sup> ion in trithiocarbonates was observed to assume values below as well as above unity, depending on the crystal field and, probably, on bond interactions between metal and sulfur.</p></div>\",\"PeriodicalId\":101180,\"journal\":{\"name\":\"Spectrochimica Acta\",\"volume\":\"22 8\",\"pages\":\"Pages 1535-1536\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1966-08-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/0371-1951(66)80152-2\",\"citationCount\":\"5\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Spectrochimica Acta\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/0371195166801522\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Spectrochimica Acta","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0371195166801522","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Die lage der nichtebenen deformationsschwingung ν2 relativ zur lage der totalsymmetrischen valenzsehwingung ν1 in trithiocarbonaten
The frequency ratio of the ν1(A1′) and νt2(E′) vibrations of the CS32− ion in trithiocarbonates was observed to assume values below as well as above unity, depending on the crystal field and, probably, on bond interactions between metal and sulfur.
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