胶载三聚氰胺:一种可回收试剂，用于选择性和无金属氧化苯甲醇

ECSOC-25 Pub Date : 2021-11-14 DOI:10.3390/ecsoc-25-11718

H. Ghafuri, Yegane Rostami, Nastaran Ghanbari, B. Abbasi, Zeinab Tajik, Nasim Amiri Ramsheh

{"title":"胶载三聚氰胺:一种可回收试剂，用于选择性和无金属氧化苯甲醇","authors":"H. Ghafuri, Yegane Rostami, Nastaran Ghanbari, B. Abbasi, Zeinab Tajik, Nasim Amiri Ramsheh","doi":"10.3390/ecsoc-25-11718","DOIUrl":null,"url":null,"abstract":": Here, novel melamine functionalized gum (gum@Melamine@Cu(II)) is synthesized and its catalytic performance is investigated in the oxidation of benzyl alcohols. The gum@Melamine was prepared through the grafting of 3-chloropropyltrimethoxysilane onto gum, followed by treatment with melamine. The synthesized gum@Melamine@Cu(II) was used to achieve an effective and selective method for the oxidation of different alcohols. All substituted benzyl alcohols were oxidized in good yields under mild conditions at room temperature. This gum@Melamine@Cu(II) has great stability and could be recycled ﬁve times without noteworthy loss of activity.","PeriodicalId":11441,"journal":{"name":"ECSOC-25","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2021-11-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Gum-Supported Melamine: A Recyclable Reagent for Selective and Metal-Free Oxidation of Benzyl Alcohols\",\"authors\":\"H. Ghafuri, Yegane Rostami, Nastaran Ghanbari, B. Abbasi, Zeinab Tajik, Nasim Amiri Ramsheh\",\"doi\":\"10.3390/ecsoc-25-11718\",\"DOIUrl\":null,\"url\":null,\"abstract\":\": Here, novel melamine functionalized gum (gum@Melamine@Cu(II)) is synthesized and its catalytic performance is investigated in the oxidation of benzyl alcohols. The gum@Melamine was prepared through the grafting of 3-chloropropyltrimethoxysilane onto gum, followed by treatment with melamine. The synthesized gum@Melamine@Cu(II) was used to achieve an effective and selective method for the oxidation of different alcohols. All substituted benzyl alcohols were oxidized in good yields under mild conditions at room temperature. This gum@Melamine@Cu(II) has great stability and could be recycled ﬁve times without noteworthy loss of activity.\",\"PeriodicalId\":11441,\"journal\":{\"name\":\"ECSOC-25\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2021-11-14\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"ECSOC-25\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.3390/ecsoc-25-11718\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"ECSOC-25","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.3390/ecsoc-25-11718","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}

引用次数: 0

摘要

本文合成了新型三聚氰胺功能化胶(gum@Melamine@Cu(II))，并对其在苯甲醇氧化中的催化性能进行了研究。将3-氯丙基三甲氧基硅烷接枝到胶上，再用三聚氰胺处理，制得gum@Melamine。利用合成的gum@Melamine@Cu(II)实现了对不同醇的有效选择性氧化。在温和的室温条件下，所有取代苯甲醇都以较高的产率被氧化。该gum@Melamine@Cu(II)具有很高的稳定性，可以循环使用五次而没有明显的活性损失。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文本刊更多论文

Gum-Supported Melamine: A Recyclable Reagent for Selective and Metal-Free Oxidation of Benzyl Alcohols

: Here, novel melamine functionalized gum (gum@Melamine@Cu(II)) is synthesized and its catalytic performance is investigated in the oxidation of benzyl alcohols. The gum@Melamine was prepared through the grafting of 3-chloropropyltrimethoxysilane onto gum, followed by treatment with melamine. The synthesized gum@Melamine@Cu(II) was used to achieve an effective and selective method for the oxidation of different alcohols. All substituted benzyl alcohols were oxidized in good yields under mild conditions at room temperature. This gum@Melamine@Cu(II) has great stability and could be recycled ﬁve times without noteworthy loss of activity.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

ECSOC-25

自引率

0.00%

发文量