{"title":"六硫酸肌醇(游离酸)在水溶液中的γ-辐射分解","authors":"M. Balakrishnan, W.J. Criddle, B.J. Jones","doi":"10.1016/0020-7055(76)90021-8","DOIUrl":null,"url":null,"abstract":"<div><p>The effects of <em>γ</em>-radiation on aqueous solutions of myo-inositol hexasulphate in the free acid form have been studied. The results have been explained on the basis of radical initiated chain processes which lead to the observed high <em>G</em>-values for the ultimate inorganic product namely the sulphate ion and to low hydrogen peroxide yields. In addition, steady-state competition procedures and pulse radiolysis experiments show that the reaction between the OH and the substrate is slow.</p></div>","PeriodicalId":100688,"journal":{"name":"International Journal for Radiation Physics and Chemistry","volume":"8 5","pages":"Pages 549-553"},"PeriodicalIF":0.0000,"publicationDate":"1976-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0020-7055(76)90021-8","citationCount":"1","resultStr":"{\"title\":\"γ-radiolysis of myo-inositol hexasulphate (free acid) in aqueous solution\",\"authors\":\"M. Balakrishnan, W.J. Criddle, B.J. Jones\",\"doi\":\"10.1016/0020-7055(76)90021-8\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The effects of <em>γ</em>-radiation on aqueous solutions of myo-inositol hexasulphate in the free acid form have been studied. The results have been explained on the basis of radical initiated chain processes which lead to the observed high <em>G</em>-values for the ultimate inorganic product namely the sulphate ion and to low hydrogen peroxide yields. In addition, steady-state competition procedures and pulse radiolysis experiments show that the reaction between the OH and the substrate is slow.</p></div>\",\"PeriodicalId\":100688,\"journal\":{\"name\":\"International Journal for Radiation Physics and Chemistry\",\"volume\":\"8 5\",\"pages\":\"Pages 549-553\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1976-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/0020-7055(76)90021-8\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"International Journal for Radiation Physics and Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/0020705576900218\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal for Radiation Physics and Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0020705576900218","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
γ-radiolysis of myo-inositol hexasulphate (free acid) in aqueous solution
The effects of γ-radiation on aqueous solutions of myo-inositol hexasulphate in the free acid form have been studied. The results have been explained on the basis of radical initiated chain processes which lead to the observed high G-values for the ultimate inorganic product namely the sulphate ion and to low hydrogen peroxide yields. In addition, steady-state competition procedures and pulse radiolysis experiments show that the reaction between the OH and the substrate is slow.
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