{"title":"羟基端基对聚合物和单体溶液振动特性的影响:衰减全反射傅里叶变换红外吸光度研究","authors":"V. Crupi, D. Majolino, P. Migliardo, V. Venuti","doi":"10.1080/13642810208223129","DOIUrl":null,"url":null,"abstract":"Abstract We studied, versus temperature, the vibrational properties of ethylene glycol (EG) (H—(O—CH2—CH2)—OH) and ethylene glycol monomethyl ether (EGmE) (CH3—(O—CH2—CH2)—OH), in solution with poly(ethylene oxide) (PEO) (H—(O—CH2—CH2)n—OH) at different concentrations, by Fourier transform infrared spectroscopy. These homologous systems differ for the number of OH end groups, in particular two for EG, and one for EGmE. Connecting the O—H stretching band shape to the different hydrogen bond imposed local environments, we clarified the role of this bond in the solute-solvent interactions, obtaining information on the quality of these solvents.","PeriodicalId":20016,"journal":{"name":"Philosophical Magazine Part B","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2002-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Influence of hydroxyl end groups on the vibrational properties of polymer and monomer solutions: An attenuated total reflectance Fourier transform infrared absorbance study\",\"authors\":\"V. Crupi, D. Majolino, P. Migliardo, V. Venuti\",\"doi\":\"10.1080/13642810208223129\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Abstract We studied, versus temperature, the vibrational properties of ethylene glycol (EG) (H—(O—CH2—CH2)—OH) and ethylene glycol monomethyl ether (EGmE) (CH3—(O—CH2—CH2)—OH), in solution with poly(ethylene oxide) (PEO) (H—(O—CH2—CH2)n—OH) at different concentrations, by Fourier transform infrared spectroscopy. These homologous systems differ for the number of OH end groups, in particular two for EG, and one for EGmE. Connecting the O—H stretching band shape to the different hydrogen bond imposed local environments, we clarified the role of this bond in the solute-solvent interactions, obtaining information on the quality of these solvents.\",\"PeriodicalId\":20016,\"journal\":{\"name\":\"Philosophical Magazine Part B\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2002-03-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Philosophical Magazine Part B\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1080/13642810208223129\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Philosophical Magazine Part B","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1080/13642810208223129","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Influence of hydroxyl end groups on the vibrational properties of polymer and monomer solutions: An attenuated total reflectance Fourier transform infrared absorbance study
Abstract We studied, versus temperature, the vibrational properties of ethylene glycol (EG) (H—(O—CH2—CH2)—OH) and ethylene glycol monomethyl ether (EGmE) (CH3—(O—CH2—CH2)—OH), in solution with poly(ethylene oxide) (PEO) (H—(O—CH2—CH2)n—OH) at different concentrations, by Fourier transform infrared spectroscopy. These homologous systems differ for the number of OH end groups, in particular two for EG, and one for EGmE. Connecting the O—H stretching band shape to the different hydrogen bond imposed local environments, we clarified the role of this bond in the solute-solvent interactions, obtaining information on the quality of these solvents.
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