I. M. Trimastiya, I. S. Negara, O. Ratnayani, I. Simpen
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引用次数: 1

摘要

PET是一种不可降解的塑料,会造成环境问题。本研究旨在利用Fenton试剂引发剂将PET与纤维素交联形成复合材料,研究在PET-纤维素复合材料混合物中,作为引发剂的Fenton试剂添加H2O2对其吸水率和在干湿土壤介质中的降解速率的影响。制备PET-纤维素复合材料的步骤是采用溶胀法精制PET,然后以fenton (H2O2/Fe2+)为引发剂,随着H2O2用量(30 g、60 g、90 g)的变化,通过自由基交联反应生成PET-纤维素复合材料。测试了复合材料在湿土介质和未处理PET控制的干土中的吸水和降解性能。用FTIR对其进行官能团分析,用SEM对其形貌进行表征。研究结果表明,利用fenton试剂制备聚对苯二甲酸乙二醇酯与纤维素交联的复合材料制备成功,随着过氧化氢用量的增加,pet -纤维素复合材料的降解速度减慢。在pet -纤维素复合材料中,H2O2用量越多,复合材料对水的吸收能力越弱。关键词:可降解,fenton (H2O2/Fe2+), PET(聚邻苯二甲酸乙二醇酯),纤维素,复合材料
本文章由计算机程序翻译,如有差异,请以英文原文为准。
KOMPOSIT DEGRADABEL POLIETILENA TEREFTALAT DENGAN SELULOSA MENGGUNAKAN REAGEN FENTON (H2O2/Fe2+)
PET is a non-degradable type of plastic that can cause environmental problems. This study aimed to form composites by cross-linking PET with cellulose using Fenton reagent initiator, finding out the effect of the addition of H2O2 on the fenton reagent used as an initiator in the mixture of PET-cellulose composites to water absorption and the rate of degradation in wet and dry soil media. The steps carried out in making PET-cellulose composites was refining PET using swelling techniques, followed by the formation of PET-cellulose composites by cross-linking through free radical reaction using fenton (H2O2/Fe2+) as the initiator with the variation of H2O2 amount (30 grams, 60 grams, 90 grams). The resulting composites were tested for water absorption and degradation properties in wet soil media and dry soil with untreated PET control. Characterization was carried out by functional group analysis using FTIR and its morphology with SEM. The results of the study showed that the composite making using the technique of cross-linking between polyethylene terephthalate and cellulose using fenton reagents was successfully carried out where the degradation rate of PET-cellulose composites slowed as the amount of hydrogen peroxide was used. In PET-cellulose composites, the more amount of H2O2 used, the weaker the absorption of the composite to water was. Keywords: degradable, fenton (H2O2/Fe2+), PET (Polyethylene Tephthalate), cellulose, composite.
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