在离子液体催化剂的存在下合成双二苯甲酸酯、双对二氯二苯甲酸酯乙二醇醚

P.M. Kerimov, O.M. Alesgerova, L.M. Saadova, G. G. Nasibova, E.M. Guliyeva
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引用次数: 0

摘要

以苯甲酸、对氯苯甲酸和乙二醇为原料,以2:1、2的比例,在110 оС温度下,在n-甲基吡拉酮-氢硫酸盐离子液体催化剂存在下,反应时间为6-7小时,合成了双二苯甲酸酯和双对二氯二苯甲酸乙二醇醚,相应的收率为82 - 92%。确定了合成的化合物醚的理化参数,并对其结构进行了光谱鉴定。对合成的复合醚进行了柴油热氧化稳定性试验。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
The synthesis of bis-dibenzoat, bis-p-dichloro-dibenzoat ethers of ethylene-glycol in the presence of ionic-liquid catalyst
Bis-dibenzoat and bis-p-dichloro-dibenzoat ethers of ethylene-glycol with 82–92 % of yield correspondingly were synthesized based on the benzoic, p-chlorobenzoic acids and ethylene-glycol in the ratio of 2:1,2, at 110 оС temperature and 6-7 hours of reaction duration in the presence of ionic liquid catalyst of n-methylpirralidon-hydrosulphate. The physical-chemical parameters of synthesized compound ethers have been specified and their structure identified spectrally. Synthesized compound ethers have been tested on the steadiness of diesel fuel against thermal oxidation.
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