P.M. Kerimov, O.M. Alesgerova, L.M. Saadova, G. G. Nasibova, E.M. Guliyeva
{"title":"在离子液体催化剂的存在下合成双二苯甲酸酯、双对二氯二苯甲酸酯乙二醇醚","authors":"P.M. Kerimov, O.M. Alesgerova, L.M. Saadova, G. G. Nasibova, E.M. Guliyeva","doi":"10.37474/0365-8554/2022-9-55-59","DOIUrl":null,"url":null,"abstract":"Bis-dibenzoat and bis-p-dichloro-dibenzoat ethers of ethylene-glycol with 82–92 % of yield correspondingly were synthesized based on the benzoic, p-chlorobenzoic acids and ethylene-glycol in the ratio of 2:1,2, at 110 оС temperature and 6-7 hours of reaction duration in the presence of ionic liquid catalyst of n-methylpirralidon-hydrosulphate. The physical-chemical parameters of synthesized compound ethers have been specified and their structure identified spectrally. Synthesized compound ethers have been tested on the steadiness of diesel fuel against thermal oxidation.","PeriodicalId":8668,"journal":{"name":"Azerbaijan Oil Industry","volume":"13 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2022-09-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"The synthesis of bis-dibenzoat, bis-p-dichloro-dibenzoat ethers of ethylene-glycol in the presence of ionic-liquid catalyst\",\"authors\":\"P.M. Kerimov, O.M. Alesgerova, L.M. Saadova, G. G. Nasibova, E.M. Guliyeva\",\"doi\":\"10.37474/0365-8554/2022-9-55-59\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Bis-dibenzoat and bis-p-dichloro-dibenzoat ethers of ethylene-glycol with 82–92 % of yield correspondingly were synthesized based on the benzoic, p-chlorobenzoic acids and ethylene-glycol in the ratio of 2:1,2, at 110 оС temperature and 6-7 hours of reaction duration in the presence of ionic liquid catalyst of n-methylpirralidon-hydrosulphate. The physical-chemical parameters of synthesized compound ethers have been specified and their structure identified spectrally. Synthesized compound ethers have been tested on the steadiness of diesel fuel against thermal oxidation.\",\"PeriodicalId\":8668,\"journal\":{\"name\":\"Azerbaijan Oil Industry\",\"volume\":\"13 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2022-09-15\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Azerbaijan Oil Industry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.37474/0365-8554/2022-9-55-59\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Azerbaijan Oil Industry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.37474/0365-8554/2022-9-55-59","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
The synthesis of bis-dibenzoat, bis-p-dichloro-dibenzoat ethers of ethylene-glycol in the presence of ionic-liquid catalyst
Bis-dibenzoat and bis-p-dichloro-dibenzoat ethers of ethylene-glycol with 82–92 % of yield correspondingly were synthesized based on the benzoic, p-chlorobenzoic acids and ethylene-glycol in the ratio of 2:1,2, at 110 оС temperature and 6-7 hours of reaction duration in the presence of ionic liquid catalyst of n-methylpirralidon-hydrosulphate. The physical-chemical parameters of synthesized compound ethers have been specified and their structure identified spectrally. Synthesized compound ethers have been tested on the steadiness of diesel fuel against thermal oxidation.