未烧陶粒的制备及其反应机理的实验研究

Su Huidong, Zhou Pengfei
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引用次数: 1

摘要

本实验采用蒸汽养护法制备免烧粉煤灰陶粒,以电厂粉煤灰、水泥、石灰、石膏为主要原料,以CaCl2、Na2SO4和NaCl为活化剂,通过单因素试验制备免烧粉煤灰陶粒,得到最佳原料用量,分析不同原料在反应体系中的作用机理。结果表明,粉煤灰、水泥、石灰、石膏、CaCl2、Na2SO4、NaCl的最佳掺量分别为16g、3.2g、1.6g、0.4g、0.1g、0.4g、0.1g。水泥和石灰可以为粉煤灰提供有效的碱性环境,但过量的水泥和石灰会降低陶粒的强度。石膏可以为体系提供Ca2+源,并具有分散剂的作用,两者都可以使体系的成分充分反应,但过量的石膏会降低陶瓷的强度。以CaCl2、Na2SO4和NaCl为活化剂,为初始体系的反应提供了充足的碱性环境,并能有效地提高陶粒的初始强度,因此添加合适的活化剂有助于陶粒强度的提高。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
The Experimental Study of Preparation of Unburned Ceramsite and Its Reaction Mechanism
This experiment adopts steam curing method to prepare unburned fly ash ceramsite£¬using power plant fly ash, cement, lime, gypsum as main raw material £¬ CaCl2, Na2SO4 and NaCl as activating agent£¬through a single factor experiment to prepare the unburned fly ash ceramsite and obtain the optimal dosage of materials, then analyzing there action mechanism of different materials in the reaction system. The results shows that the optimum dosage of fly ash, cement, lime, gypsum, CaCl2, Na2SO4 and NaCl is 16g, 3.2g, 1.6g, 0.4g, 0.1g, 0.4g, 0.1g respectively. And, cement and lime can provide an effective alkaline environment to fly ash£¬butexcessive amount of cement and lime will lower the strength of ceramsite. Gypsum can provide Ca2+ sources to the system£¬and have the role of dispersant, both of which can make the ingredients of system have a full reaction, but excessive gypsum can reduce the ceramic strength. CaCl2, Na2SO4 and NaCl as activating agent, provide a sufficient alkaline environment for the reaction of the initial system, and can efficiently increase the initial strength of ceramsite, so it is helpful for the strength of ceramsite to add some suitable activating agent.
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