固相反应法制备Li4SrCa(SiO4)2: Eu3+红色荧光粉的结构、组成及发光研究

D. Sahu, D. P. Bisen, N. Brahme, Kanchan Tiwari, Aastha Sahu
{"title":"固相反应法制备Li4SrCa(SiO4)2: Eu3+红色荧光粉的结构、组成及发光研究","authors":"D. Sahu, D. P. Bisen, N. Brahme, Kanchan Tiwari, Aastha Sahu","doi":"10.52228/jrub.2023-36-1-10","DOIUrl":null,"url":null,"abstract":"\n In this paper, Eu3+ doped phosphor Li4SrCa(SiO4)2 is successfully synthesized via a solid-state reaction method at high temperatures. Structure characterization is determined using X-ray diffraction (XRD). Surface morphology was analyzed using Field emission scanning electron microscopy(FESEM). The EDX spectra confirm the elements present in Li4SrCa(SiO4)2:Eu3+ phosphor. Photoluminescence(PL) spectra of Li4SrCa(SiO4)2:Eu3+ phosphor was efficiently excited by UV range 220-450nm and under the excitation 395nm phosphors shows good intensity with an orange-red intense peak at 591nm and 619 nm was due to 4D0-7F1 and 4D0-7F2 transition respectively. Commission International del’ Eclairage (CIE) color coordinate was calculated, which confirms the Eu3+ doped phosphor with a CIE value of (x=0.6259, y=0.3737). This phosphor is considered to be a new promising orange-red emitting phosphor for WLEDs application. This phosphor may be used for solid-state lighting. \n","PeriodicalId":17214,"journal":{"name":"Journal of Ravishankar University (PART-B)","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2023-07-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Structural, Compositional and Photoluminescence Studies of Li4SrCa(SiO4)2: Eu3+ Red Phosphor Synthesized by Solid State Reaction Method\",\"authors\":\"D. Sahu, D. P. Bisen, N. Brahme, Kanchan Tiwari, Aastha Sahu\",\"doi\":\"10.52228/jrub.2023-36-1-10\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"\\n In this paper, Eu3+ doped phosphor Li4SrCa(SiO4)2 is successfully synthesized via a solid-state reaction method at high temperatures. Structure characterization is determined using X-ray diffraction (XRD). Surface morphology was analyzed using Field emission scanning electron microscopy(FESEM). The EDX spectra confirm the elements present in Li4SrCa(SiO4)2:Eu3+ phosphor. Photoluminescence(PL) spectra of Li4SrCa(SiO4)2:Eu3+ phosphor was efficiently excited by UV range 220-450nm and under the excitation 395nm phosphors shows good intensity with an orange-red intense peak at 591nm and 619 nm was due to 4D0-7F1 and 4D0-7F2 transition respectively. Commission International del’ Eclairage (CIE) color coordinate was calculated, which confirms the Eu3+ doped phosphor with a CIE value of (x=0.6259, y=0.3737). This phosphor is considered to be a new promising orange-red emitting phosphor for WLEDs application. This phosphor may be used for solid-state lighting. \\n\",\"PeriodicalId\":17214,\"journal\":{\"name\":\"Journal of Ravishankar University (PART-B)\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2023-07-13\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Ravishankar University (PART-B)\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.52228/jrub.2023-36-1-10\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Ravishankar University (PART-B)","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.52228/jrub.2023-36-1-10","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0

摘要

本文采用固相反应方法,在高温下成功合成了Eu3+掺杂的荧光粉Li4SrCa(SiO4)2。结构表征采用x射线衍射(XRD)确定。利用场发射扫描电镜(FESEM)分析了表面形貌。EDX光谱证实了Li4SrCa(SiO4)2:Eu3+荧光粉中存在的元素。Li4SrCa(SiO4)2:Eu3+荧光粉的光致发光光谱在220 ~ 450nm范围内被有效激发,在395nm激发下荧光粉表现出良好的光致发光强度,在591nm和619nm处分别由于4D0-7F1和4D0-7F2跃迁而出现橘红色的光致发光峰。计算了CIE (Commission International del’Eclairage)颜色坐标,确认了Eu3+掺杂荧光粉的CIE值为(x=0.6259, y=0.3737)。该荧光粉被认为是一种具有较好应用前景的橙红色发光荧光粉。这种荧光粉可用于固态照明。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Structural, Compositional and Photoluminescence Studies of Li4SrCa(SiO4)2: Eu3+ Red Phosphor Synthesized by Solid State Reaction Method
In this paper, Eu3+ doped phosphor Li4SrCa(SiO4)2 is successfully synthesized via a solid-state reaction method at high temperatures. Structure characterization is determined using X-ray diffraction (XRD). Surface morphology was analyzed using Field emission scanning electron microscopy(FESEM). The EDX spectra confirm the elements present in Li4SrCa(SiO4)2:Eu3+ phosphor. Photoluminescence(PL) spectra of Li4SrCa(SiO4)2:Eu3+ phosphor was efficiently excited by UV range 220-450nm and under the excitation 395nm phosphors shows good intensity with an orange-red intense peak at 591nm and 619 nm was due to 4D0-7F1 and 4D0-7F2 transition respectively. Commission International del’ Eclairage (CIE) color coordinate was calculated, which confirms the Eu3+ doped phosphor with a CIE value of (x=0.6259, y=0.3737). This phosphor is considered to be a new promising orange-red emitting phosphor for WLEDs application. This phosphor may be used for solid-state lighting.
求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
自引率
0.00%
发文量
0
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信