Tiamina Nasution, Akhir Mauludin Pulungan, Yuli Asih Wiliranti, J. Sihombing, A. Pulungan
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引用次数: 2
摘要
在本研究中,采用Z-AH和Z-OH沸石催化剂进行生物柴油的合成,以获得更便宜和环保的工艺。以印尼Sarulla天然沸石(Z-AS)为原料,用一定量的HCl 3 M和NaOH 2 M进行化学活化,然后在500℃下用氮气煅烧4 h,得到Z-AH和Z-OH催化剂。采用FT-IR和XRD对催化剂进行了表征。橡胶籽油在30℃、60℃和90℃的温度下转化为生物柴油。甲醇与橡胶籽油的比例为6:1 (v / v),催化剂浓度为1% wt。XRD和FTIR数据表明,活化Z-AS提高了沸石的结晶度,且不破坏沸石的骨架结构。Z-AH催化剂的催化活性优于Z-OH催化剂,生物柴油产品的转化率为69.79%。
Synthesis of Biodiesel From Rubber Seed Oil with Acid and Base Activated Natural Zeolite Catalyst
In this study, biodiesel synthesis was carried out using Z-AH and Z-OH Zeolite catalysts to obtain a cheaper and environmentally friendly process. The catalysts were prepared from Sarulla Indonesian natural zeolite (Z-AS) through a chemical activation process with certain HCl 3 M and NaOH 2 M, then calcined at 500°C with Nitrogen gas for 4 hours to obtain Z-AH ang Z-OH catalyst. The catalysts were characterized by FT-IR and XRD. The conversion of rubber seed oil into biodiesel was carried out at temperature of 30 oC, 60 oC and 90 oC. The ratio of methanol: rubber seed oil is 6: 1 (v / v) and the catalyst concentration used is 1% wt. The XRD and FTIR data show that Z-AS activation increases the crystallinity of zeolite and does not damage the zeolite skeletal structure.The Z-AH catalyst has a better catalytic activity than the Z-OH catalyst with the conversion value of the biodiesel product obtained at 69.79%.