{"title":"三甲基膦与溴乙酸乙酯合成的磷盐铜(II)配合物的立体合成与鉴定","authors":"A. Naghipour, Abozar Bastami, A. Ezati","doi":"10.14196/SJR.V6I7.2421","DOIUrl":null,"url":null,"abstract":"Phosphonium salts have the general formula and are derived from the sub-ion phosphonium tetrahedral , such as phosphonium iodide . Generally, phosphonium is attributed to an organic derivative, such as tetra-phenyl phosphonium chloride and tetra tetra-methylphosphonium iodide. In this project, the phosphonium compounds [C 2 H 5 COO (CH 2 PPh 3 Br)] and its copper (II) complex [C 2 H 5 COO (CH 2 PP 3 Br)] [Cu 2 Cl 6 ] were prepared and identified. Phosphonium species were prepared from the reaction of ethyl bromoacetate with terphenylphosphine. Then the final compounds were prepared using the reaction between the phosphonium compound with Na 2 [Cu 2 Cl 6 ]. Then, using spectroscopic methods, preparation of these compounds was investigated.","PeriodicalId":21707,"journal":{"name":"Scientific Journal of Review","volume":"89 1","pages":"535-541"},"PeriodicalIF":0.0000,"publicationDate":"2017-07-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis and identification of copper (II) complexes using phosphonium salt resulting from the combination of trinylphosphine and ethyl bromoacetate, using stereoscopic methods\",\"authors\":\"A. Naghipour, Abozar Bastami, A. Ezati\",\"doi\":\"10.14196/SJR.V6I7.2421\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Phosphonium salts have the general formula and are derived from the sub-ion phosphonium tetrahedral , such as phosphonium iodide . Generally, phosphonium is attributed to an organic derivative, such as tetra-phenyl phosphonium chloride and tetra tetra-methylphosphonium iodide. In this project, the phosphonium compounds [C 2 H 5 COO (CH 2 PPh 3 Br)] and its copper (II) complex [C 2 H 5 COO (CH 2 PP 3 Br)] [Cu 2 Cl 6 ] were prepared and identified. Phosphonium species were prepared from the reaction of ethyl bromoacetate with terphenylphosphine. Then the final compounds were prepared using the reaction between the phosphonium compound with Na 2 [Cu 2 Cl 6 ]. Then, using spectroscopic methods, preparation of these compounds was investigated.\",\"PeriodicalId\":21707,\"journal\":{\"name\":\"Scientific Journal of Review\",\"volume\":\"89 1\",\"pages\":\"535-541\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2017-07-18\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Scientific Journal of Review\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.14196/SJR.V6I7.2421\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Scientific Journal of Review","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.14196/SJR.V6I7.2421","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Synthesis and identification of copper (II) complexes using phosphonium salt resulting from the combination of trinylphosphine and ethyl bromoacetate, using stereoscopic methods
Phosphonium salts have the general formula and are derived from the sub-ion phosphonium tetrahedral , such as phosphonium iodide . Generally, phosphonium is attributed to an organic derivative, such as tetra-phenyl phosphonium chloride and tetra tetra-methylphosphonium iodide. In this project, the phosphonium compounds [C 2 H 5 COO (CH 2 PPh 3 Br)] and its copper (II) complex [C 2 H 5 COO (CH 2 PP 3 Br)] [Cu 2 Cl 6 ] were prepared and identified. Phosphonium species were prepared from the reaction of ethyl bromoacetate with terphenylphosphine. Then the final compounds were prepared using the reaction between the phosphonium compound with Na 2 [Cu 2 Cl 6 ]. Then, using spectroscopic methods, preparation of these compounds was investigated.