木材成分是合成有用化合物、产品和试剂的含戊原料的来源

I. Chetvertneva, O. Karimov, G. Teptereva, N. S. Tivas, E. Movsumzade, E. Babayev
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引用次数: 0

摘要

本文考虑了木材加工、农业废弃物、纸浆和造纸工业废弃物的主要成分和产物,认为它们是含戊糖资源可再生的国内原料来源。文章详细介绍了木材作为天然聚合物的结构成分,其中含有芳香和碳水化合物部分。值得注意的是,这些聚合物有希望作为生产有用化学产品的原料。考虑了木质素、纤维素和半纤维素在木材机械和结构性能设计中的作用。本文考虑了木质素单体单元磺化反应随介质pH值的变化特征:酸性、中性和碱性。亚硫酸盐蒸煮过程中木材脱木质素过程中主要有三个反应与木质素同时发生,即磺化反应、水解破坏反应和缩合反应。结果表明,木质素-半纤维素基质包含三种相互连接的网状结构:木质素本身;木质素与半纤维素共价键的网络,其结构是由于氢键和木质素与半纤维素的物理相互作用的力量而获得的。介绍了木质素磺酸-苯丙烷单体芳链在木材脱木质素过程中的化学转化特点,以及木材原料在亚硫酸盐和中性亚硫酸盐条件下脱木质素的主要化学反应。提出了碳水化合物部分组成中单糖的定量测定方法。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
WOOD COMPONENTS AS SOURCES OF PENTO-CONTAINING RAW MATERIALS FOR SYNTHESIS OF USEFUL COMPOUNDS, PRODUCTS AND REAGENTS
The paper considers the main components and products of wood processing, agricultural waste, pulp and paper industry waste and qualifies them as sources of pentose-containing resource-renewable domestic raw materials. The article describes in detail the structural components of wood as a natural polymer, which contains aromatic and carbohydrate parts. It is noted that these poly-mers are promising as raw materials for the production of useful chemical products. The role of lignin, cellolose and hemicellulose in the design of mechanical and structural properties of wood is considered. The article considers the features of the sulfonation reactions of the lignin monomer unit depending on the pH of the medium: acidic, neutral and alkaline. There are three main reac-tions that occur simultaneously with lignin in the process of wood delignification during sulfite cooking, such as the sulfonation reaction, the hydrolytic destruction reaction, and the condensation reaction. It is shown that the lignin-hemicellulose matrix contains three types of interconnected mesh structures: the lignin itself; a network of covalent bonds of lignin with hemicelluloses, and a network whose structure is obtained due to the hydrogen bond and the forces of the physical inter-action of lignin and hemicelluloses. The features of chemical transformations of the monomeric aromatic link of lignosulfonate – phenylpropane unit in the processes of wood delignification, the main chemical reactions of wood raw material delignification under the conditions of sulfite and neutral-sulfite brews are shown. The method of quantitative determination of monosaccharides in the composition of the carbohydrate part is proposed.
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