一些杂环聚合物和聚硅氧烷

Feng-cai Lu
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引用次数: 18

摘要

芳香族杂环聚合物和聚硅氧烷具有优异的热学、力学和绝缘性能,在航空航天、电子、制造和化工等领域作为多用途结构和功能材料具有广泛而良好的应用前景。本文综述了几种重要的芳香族杂环聚合物:聚苯基喹啉类(PPQs)、聚三嗪类(PPTs)、聚吡咯酮类(PYs)、聚酰亚胺类(PIs)、聚酰胺酰亚胺类(PAIs)、聚苯并咪唑类(ppi);和聚硅氧烷。它们全部或部分都能满足上述高技术领域的需求。相信今后这些聚合物的研究和应用将不断得到发展。我们的重点是(1)新单体和聚合物的合成;(2)开发新的合成路线;(3)聚合物新性质的发现;(4)用这些聚合物甚至杂环化合物改性单体铸造尼龙(MC尼龙、聚己内酰胺)。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Some Heterocyclic Polymers and Polysiloxanes
Aromatic heterocyclic polymers and polysiloxanes exhibit excellent thermal, mechanical, and insulating properties, having both wide and good potential use as multipurpose structural and functional materials in aerospace, electronic, manufacturing, and chemical industries. This paper briefly reviews our research work on several important aromatic heterocyclic polymers: polyphenylquinoxalines (PPQs), polytriazines (PPTs), polypyrrolones (PYs), polyimides (PIs), polyamide-imides (PAIs), polybenzimidazoles (PBIs); and polysiloxane. Either all or some of them can meet the needs in the above-mentioned high-technology areas. It is believed that the research work and applications of these polymers will be continually developed in the future. We focused our attention on (1) the syntheses of new monomers and polymers; (2) development of new synthetic routes; (3) discovery of new properties of polymers; (4) modification of monomer casting nylon (MC nylon, polycaprolactam) by these polymers and even heterocyclic comp...
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