溶剂热处理蓝菖蒲叶提取物绿色合成荧光碳点

ECSOC-25 Pub Date : 2021-11-13 DOI:10.3390/ecsoc-25-11648
P. Jana, A. Dev
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引用次数: 1

摘要

本研究采用溶剂热法,在160℃的烘箱中处理4 h,合成了荧光碳点(CDs)。在这里,布氏树的叶子是一种可再生的碳源。将得到的黑褐色CDs溶液离心,上清用注射器过滤器(0.22µm)过滤。然后将CDs溶液在真空烘箱中干燥得到粉末。采用紫外可见光谱、荧光光谱、傅里叶红外光谱、zeta电位、x射线衍射等技术对合成的CDs进行了表征。所制备的CDs溶液在日光下呈褐色,在紫外光下呈绿色荧光。紫外可见吸收光谱显示了CDs在257 nm和356nm处的特征肩峰。在荧光光谱中,观察到CDs的激发依赖发射行为,这是CDs的显著特征之一。负zeta电位和FTIR特征峰表明CDs表面存在羰基、胺和羟基官能团。XRD谱在2θ=19°处显示出宽峰,表明CDs的无定形性质与前期报道相似。由于我们已经用一种可再生的、丰富的前体合成了表面功能化的荧光碳点,这种方法可以在大规模合成碳点的同时降低成本,并且在药物输送领域有潜在的应用前景。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Green Synthesis of Fluorescent Carbon Dots through Solvothermal Treatment of Buchnania lanzan Leaf Extract
: In the present work we have synthesized fluorescent carbon dots (CDs) through solvothermal treatment of Buchnania lanzan leaves extract at 160 °C for 4 h in oven. Here, Buchnania lanzan leaves serve as a renewable source of carbon. The obtained blackish brown CDs solution was centrifuged and the supernatant was filtered through syringe filter (0.22 µm). Further, the CDs solution was dried in vacuum oven to obtain powder. The synthesized CDs were characterized by different techniques including UV-Visible spectroscopy, fluorescence spectroscopy, fourier trans-form infrared (FTIR), zeta potential, x-ray diffraction (XRD). The as prepared CDs solution was found brownish colored in day light while exhibited green fluorescence under UV light. UV-Visible absorption spectrum displayed characteristic shoulder peaks of CDs at 257 nm and at 356 nm. In the fluorescence spectra, excitation dependent emission behaviour of CDs was seen, which is one of the distinct characteristics of CDs. The negative zeta potential and characteristic peaksin FTIR, suggested presence of carbonyl, amine and hydroxyl functional groups on the CDs surface. XRD spectrum exhibited broad peak at 2θ=19°, suggesting amorphous nature of CDs similar as reported in earlier works. As we have synthesized surface functionalized fluorescent carbon dots from a renewable and abundant precursor, this method can be highly useful in large scale synthesis of carbon dots with reduced costs and will find potential applications in the field of drug delivery,
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