V. Tarabanko, I. Simakova, M. Smirnova, K. L. Kaygorodov
{"title":"糠醛缩二乙酯催化加氢制糠醛乙基醚","authors":"V. Tarabanko, I. Simakova, M. Smirnova, K. L. Kaygorodov","doi":"10.17516/1998-2836-0237","DOIUrl":null,"url":null,"abstract":"The process of catalytic hydrogenation of furfural diethyl acetal to ethyl furfuryl ether on the different catalysts (palladium, palladium-rhenium and copper-ruthenium on Sibunit in reduced forms) was studied. It was found that hydrogenation of the furan ring with the formation of THF diethyl acetal occurs on all the catalysts. Ethyl furfuryl ether becomes the main product while carrying on the second hydrogenation cycle on spent palladium catalyst (yield and selectivity up to 55 % and 85 %, respectively)","PeriodicalId":16999,"journal":{"name":"Journal of Siberian Federal University. Chemistry","volume":"220 1","pages":""},"PeriodicalIF":0.5000,"publicationDate":"2021-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"2","resultStr":"{\"title\":\"Catalytic Hydrogenation of Furfural Diethyl Acetal to Ethyl Furfuryl Ether\",\"authors\":\"V. Tarabanko, I. Simakova, M. Smirnova, K. L. Kaygorodov\",\"doi\":\"10.17516/1998-2836-0237\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The process of catalytic hydrogenation of furfural diethyl acetal to ethyl furfuryl ether on the different catalysts (palladium, palladium-rhenium and copper-ruthenium on Sibunit in reduced forms) was studied. It was found that hydrogenation of the furan ring with the formation of THF diethyl acetal occurs on all the catalysts. Ethyl furfuryl ether becomes the main product while carrying on the second hydrogenation cycle on spent palladium catalyst (yield and selectivity up to 55 % and 85 %, respectively)\",\"PeriodicalId\":16999,\"journal\":{\"name\":\"Journal of Siberian Federal University. Chemistry\",\"volume\":\"220 1\",\"pages\":\"\"},\"PeriodicalIF\":0.5000,\"publicationDate\":\"2021-09-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"2\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Siberian Federal University. Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.17516/1998-2836-0237\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Siberian Federal University. Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.17516/1998-2836-0237","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Catalytic Hydrogenation of Furfural Diethyl Acetal to Ethyl Furfuryl Ether
The process of catalytic hydrogenation of furfural diethyl acetal to ethyl furfuryl ether on the different catalysts (palladium, palladium-rhenium and copper-ruthenium on Sibunit in reduced forms) was studied. It was found that hydrogenation of the furan ring with the formation of THF diethyl acetal occurs on all the catalysts. Ethyl furfuryl ether becomes the main product while carrying on the second hydrogenation cycle on spent palladium catalyst (yield and selectivity up to 55 % and 85 %, respectively)