{"title":"混合pentahaloantimonates (3)","authors":"N.K. Jha , Amrita Kumari, R.S. Prasad","doi":"10.1016/0022-1902(81)80069-3","DOIUrl":null,"url":null,"abstract":"<div><p>Mixed pentahaloantimonates(III) formulated as R<sub>2</sub>(SbX<sub>3</sub>Y<sub>2</sub>) (R = substituted ammonium ion and X and YCl, Br or I) and [(C<sub>2</sub>H<sub>5</sub>)<sub>4</sub>N]<sub>2</sub> [SbCl<sub>3</sub>BrI] have been isolated from non-aqueous media by the interaction of the antimony trihalide and the substituted ammonium halide. The reaction stoichiometry between SbX<sub>3</sub> (XCl, Br) and substituted ammonium halide was determined by conductimetric titrations. These complexes were characterised by chemical analysis, melting points, conductance, TGA, far IR and electronic spectra.</p></div>","PeriodicalId":16275,"journal":{"name":"Journal of Inorganic and Nuclear Chemistry","volume":"43 12","pages":"Pages 3095-3097"},"PeriodicalIF":0.0000,"publicationDate":"1981-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-1902(81)80069-3","citationCount":"1","resultStr":"{\"title\":\"Mixed pentahaloantimonates(III)\",\"authors\":\"N.K. Jha , Amrita Kumari, R.S. Prasad\",\"doi\":\"10.1016/0022-1902(81)80069-3\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Mixed pentahaloantimonates(III) formulated as R<sub>2</sub>(SbX<sub>3</sub>Y<sub>2</sub>) (R = substituted ammonium ion and X and YCl, Br or I) and [(C<sub>2</sub>H<sub>5</sub>)<sub>4</sub>N]<sub>2</sub> [SbCl<sub>3</sub>BrI] have been isolated from non-aqueous media by the interaction of the antimony trihalide and the substituted ammonium halide. The reaction stoichiometry between SbX<sub>3</sub> (XCl, Br) and substituted ammonium halide was determined by conductimetric titrations. These complexes were characterised by chemical analysis, melting points, conductance, TGA, far IR and electronic spectra.</p></div>\",\"PeriodicalId\":16275,\"journal\":{\"name\":\"Journal of Inorganic and Nuclear Chemistry\",\"volume\":\"43 12\",\"pages\":\"Pages 3095-3097\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1981-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/0022-1902(81)80069-3\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Inorganic and Nuclear Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/0022190281800693\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Inorganic and Nuclear Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0022190281800693","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Mixed pentahaloantimonates(III) formulated as R2(SbX3Y2) (R = substituted ammonium ion and X and YCl, Br or I) and [(C2H5)4N]2 [SbCl3BrI] have been isolated from non-aqueous media by the interaction of the antimony trihalide and the substituted ammonium halide. The reaction stoichiometry between SbX3 (XCl, Br) and substituted ammonium halide was determined by conductimetric titrations. These complexes were characterised by chemical analysis, melting points, conductance, TGA, far IR and electronic spectra.
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