M. Kukade, N. Gavade, A. Kadam, W. Chandane, K. Garadkar, A. J. Bodake
{"title":"磁性可回收钴铁氧体纳米颗粒作为合成1-氧-六羟基蒽的非均相催化剂","authors":"M. Kukade, N. Gavade, A. Kadam, W. Chandane, K. Garadkar, A. J. Bodake","doi":"10.14233/AJOMC.2019.AJOMC-P207","DOIUrl":null,"url":null,"abstract":"In present study, magnetically separable cobalt ferrite nanoparticles (CoFe2O4·NPs) have been prepared by low cost chemical precipitation method and reported as reusable, proficient heterogeneous catalyst for the synthesis of 1-oxo-hexahydroxanthenes among other ferrites. The structural and morphological studies by X-ray diffraction and scanning electron microscopy confirmed the formation of CoFe2O4 nanoparticles. The current protocol evaluated a proficient catalyst for reaction between various salicylaldehydes and 1,3-diketones. The ambient reaction conditions, shorter reaction time, good to excellent yields of the products, ease of purification of the products and reusa-bility of catalyst up to five catalytic cycles without significant loss of catalytic activity making the current protocol promising for its practical application.","PeriodicalId":8846,"journal":{"name":"Asian Journal of Organic & Medicinal Chemistry","volume":"198 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2019-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"Magnetically Retrievable Cobalt Ferrite Nanoparticles as Heterogeneous Catalyst for Synthesis of 1-Oxo-hexahydroxanthenes\",\"authors\":\"M. Kukade, N. Gavade, A. Kadam, W. Chandane, K. Garadkar, A. J. Bodake\",\"doi\":\"10.14233/AJOMC.2019.AJOMC-P207\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"In present study, magnetically separable cobalt ferrite nanoparticles (CoFe2O4·NPs) have been prepared by low cost chemical precipitation method and reported as reusable, proficient heterogeneous catalyst for the synthesis of 1-oxo-hexahydroxanthenes among other ferrites. The structural and morphological studies by X-ray diffraction and scanning electron microscopy confirmed the formation of CoFe2O4 nanoparticles. The current protocol evaluated a proficient catalyst for reaction between various salicylaldehydes and 1,3-diketones. The ambient reaction conditions, shorter reaction time, good to excellent yields of the products, ease of purification of the products and reusa-bility of catalyst up to five catalytic cycles without significant loss of catalytic activity making the current protocol promising for its practical application.\",\"PeriodicalId\":8846,\"journal\":{\"name\":\"Asian Journal of Organic & Medicinal Chemistry\",\"volume\":\"198 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2019-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Asian Journal of Organic & Medicinal Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.14233/AJOMC.2019.AJOMC-P207\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Asian Journal of Organic & Medicinal Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.14233/AJOMC.2019.AJOMC-P207","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Magnetically Retrievable Cobalt Ferrite Nanoparticles as Heterogeneous Catalyst for Synthesis of 1-Oxo-hexahydroxanthenes
In present study, magnetically separable cobalt ferrite nanoparticles (CoFe2O4·NPs) have been prepared by low cost chemical precipitation method and reported as reusable, proficient heterogeneous catalyst for the synthesis of 1-oxo-hexahydroxanthenes among other ferrites. The structural and morphological studies by X-ray diffraction and scanning electron microscopy confirmed the formation of CoFe2O4 nanoparticles. The current protocol evaluated a proficient catalyst for reaction between various salicylaldehydes and 1,3-diketones. The ambient reaction conditions, shorter reaction time, good to excellent yields of the products, ease of purification of the products and reusa-bility of catalyst up to five catalytic cycles without significant loss of catalytic activity making the current protocol promising for its practical application.