S. Qu, Ming Mei, W. Cao, R. K. Pan, Y. Qi, Lei Zhang, Xunzhong Shang
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Exothermic effect of entropy change in second-order phase transition ferroelectrics
Abstract Exothermic effect of entropy change by dipole orintation upon E in T-C second order phase transition ferroelectrics is modeled with statistic method. Formula of entropy change and temperature change were derived, showing sharp drop of entropy in higher temperature for higher E, exothermic peak shifts to high temperature with E, and 180° turning of dipole with a critical electric field prevails entropy change in ferroelectric phase, while 180° turning dominates entropy change in paraelectric phase. The results of numerical simulation can explain regulation of heating effect of the ferroelectrics. Morphotropic phase boundary will possess giant exothermic effect in principle.
期刊介绍:
Ferroelectrics Letters is a separately published section of the international journal Ferroelectrics. Both sections publish theoretical, experimental and applied papers on ferroelectrics and related materials, including ferroelastics, ferroelectric ferromagnetics, electrooptics, piezoelectrics, pyroelectrics, nonlinear dielectrics, polymers and liquid crystals.
Ferroelectrics Letters permits the rapid publication of important, quality, short original papers on the theory, synthesis, properties and applications of ferroelectrics and related materials.