异质外延薄膜模型的推导

IF 16.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY
E. Davoli, Paolo Piovano
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引用次数: 11

摘要

刚性衬底上外延应变薄膜的变分模型是通过从过渡层设置的{\Gamma}收敛和从文献中可用于规则配置的锐界面描述的松弛导出的。该模型的特点是一个构型能量,它解释了负责薄膜形状的两个竞争机制。一方面,薄膜和衬底之间的晶格不匹配会产生较大的应力,并且由于薄膜原子移动释放弹性能而可能出现波纹。另一方面,更平坦的轮廓可以使表面能最小化。给出了能量最优膜形的一些第一正则性结果。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Derivation of a heteroepitaxial thin-film model
A variational model for epitaxially-strained thin films on rigid substrates is derived both by {\Gamma}-convergence from a transition-layer setting, and by relaxation from a sharp-interface description available in the literature for regular configurations. The model is characterized by a configurational energy that accounts for both the competing mechanisms responsible for the film shape. On the one hand, the lattice mismatch between the film and the substrate generate large stresses, and corrugations may be present because film atoms move to release the elastic energy. On the other hand, flatter profiles may be preferable to minimize the surface energy. Some first regularity results are presented for energetically-optimal film profiles.
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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