{"title":"汽化焓精确表达式的推论","authors":"A. A. Sobko","doi":"10.1155/2011/945047","DOIUrl":null,"url":null,"abstract":"A problem on determining effective volumes for atoms and molecules becomes actual due to rapidly developing nanotechnologies. In the present study an exact expression for enthalpy of vaporization is obtained, from which an exact expression is derived for effective volumes of atoms and molecules, and under certain assumptions on the form of an atom (molecule) it is possible to find their linear dimensions. The accuracy is only determined by the accuracy of measurements of thermodynamic parameters at the critical point.","PeriodicalId":17290,"journal":{"name":"Journal of Thermodynamics","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2011-05-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Corollary from the Exact Expression for Enthalpy of Vaporization\",\"authors\":\"A. A. Sobko\",\"doi\":\"10.1155/2011/945047\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"A problem on determining effective volumes for atoms and molecules becomes actual due to rapidly developing nanotechnologies. In the present study an exact expression for enthalpy of vaporization is obtained, from which an exact expression is derived for effective volumes of atoms and molecules, and under certain assumptions on the form of an atom (molecule) it is possible to find their linear dimensions. The accuracy is only determined by the accuracy of measurements of thermodynamic parameters at the critical point.\",\"PeriodicalId\":17290,\"journal\":{\"name\":\"Journal of Thermodynamics\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2011-05-24\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Thermodynamics\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1155/2011/945047\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Thermodynamics","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1155/2011/945047","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Corollary from the Exact Expression for Enthalpy of Vaporization
A problem on determining effective volumes for atoms and molecules becomes actual due to rapidly developing nanotechnologies. In the present study an exact expression for enthalpy of vaporization is obtained, from which an exact expression is derived for effective volumes of atoms and molecules, and under certain assumptions on the form of an atom (molecule) it is possible to find their linear dimensions. The accuracy is only determined by the accuracy of measurements of thermodynamic parameters at the critical point.