M.J. den Exter, J.C. Jansen, H. van Bekkum, A. Zikánova
{"title":"全硅八环Clathrasil DD3R的合成与表征与亲水性沸石A的吸附性能比较","authors":"M.J. den Exter, J.C. Jansen, H. van Bekkum, A. Zikánova","doi":"10.1016/S0144-2449(97)00115-2","DOIUrl":null,"url":null,"abstract":"<div><p>The adsorption properties of the clathrasil Deca-dodecasil 3R (DD3R) have been studied. This porous tectosilicate becomes microporous when the organic template 1-adamantanamine is removed by calcination, which gives this clathrasil zeolitical properties. By means of adsorption of water, DD3R has been proven to be very hydrophobic. These adsorption data, together with the isosteric heats of adsorption of carbon dioxide at different loadings, reveal the absence of strong adsorption sites for polar or polarizable molecules, in contrast to the adsorbent zeolite A.</p></div>","PeriodicalId":23983,"journal":{"name":"Zeolites","volume":"19 5","pages":"Pages 353-358"},"PeriodicalIF":0.0000,"publicationDate":"1997-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/S0144-2449(97)00115-2","citationCount":"39","resultStr":"{\"title\":\"Synthesis and characterization of the all-silica 8-ring Clathrasil DD3R comparison of adsorption properties with the hydrophilic zeolite A\",\"authors\":\"M.J. den Exter, J.C. Jansen, H. van Bekkum, A. Zikánova\",\"doi\":\"10.1016/S0144-2449(97)00115-2\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The adsorption properties of the clathrasil Deca-dodecasil 3R (DD3R) have been studied. This porous tectosilicate becomes microporous when the organic template 1-adamantanamine is removed by calcination, which gives this clathrasil zeolitical properties. By means of adsorption of water, DD3R has been proven to be very hydrophobic. These adsorption data, together with the isosteric heats of adsorption of carbon dioxide at different loadings, reveal the absence of strong adsorption sites for polar or polarizable molecules, in contrast to the adsorbent zeolite A.</p></div>\",\"PeriodicalId\":23983,\"journal\":{\"name\":\"Zeolites\",\"volume\":\"19 5\",\"pages\":\"Pages 353-358\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1997-11-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/S0144-2449(97)00115-2\",\"citationCount\":\"39\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Zeolites\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0144244997001152\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Zeolites","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0144244997001152","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Synthesis and characterization of the all-silica 8-ring Clathrasil DD3R comparison of adsorption properties with the hydrophilic zeolite A
The adsorption properties of the clathrasil Deca-dodecasil 3R (DD3R) have been studied. This porous tectosilicate becomes microporous when the organic template 1-adamantanamine is removed by calcination, which gives this clathrasil zeolitical properties. By means of adsorption of water, DD3R has been proven to be very hydrophobic. These adsorption data, together with the isosteric heats of adsorption of carbon dioxide at different loadings, reveal the absence of strong adsorption sites for polar or polarizable molecules, in contrast to the adsorbent zeolite A.
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