{"title":"硅负载羧甲基纤维素-铂配合物在温和反应条件下催化茴香醇选择性加氢制环己基甲基醚","authors":"Li-Ming Tang, Zhao-Hong Meng, Mei-Yu Huang, Ying-Yan Jiang","doi":"10.1016/0923-1137(94)00090-R","DOIUrl":null,"url":null,"abstract":"<div><p>Selective hydrogenation of anisol to cyclohexyl methyl ether in 100% yield has been achieved by a new natural polymer catalyst, silica-supported carboxymethyl cellulose-platinum complex (SiO<sub>2</sub>CMCPt) at 30°C and 1 atm mild reaction conditions. The <span><math><mtext>COO</mtext><mtext>Pt</mtext></math></span> ratio, temperature and solvent had great influence on the reaction. The catalyst was stable during the reaction, its catalytic properties were little changed after being reused 4 times.</p></div>","PeriodicalId":20864,"journal":{"name":"Reactive Polymers","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"1995-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0923-1137(94)00090-R","citationCount":"4","resultStr":"{\"title\":\"Selective hydrogenation of anisol to cyclohexyl methyl ether catalyzed by a silica-supported carboxymethyl cellulose-platinum complex under mild reaction conditions\",\"authors\":\"Li-Ming Tang, Zhao-Hong Meng, Mei-Yu Huang, Ying-Yan Jiang\",\"doi\":\"10.1016/0923-1137(94)00090-R\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Selective hydrogenation of anisol to cyclohexyl methyl ether in 100% yield has been achieved by a new natural polymer catalyst, silica-supported carboxymethyl cellulose-platinum complex (SiO<sub>2</sub>CMCPt) at 30°C and 1 atm mild reaction conditions. The <span><math><mtext>COO</mtext><mtext>Pt</mtext></math></span> ratio, temperature and solvent had great influence on the reaction. The catalyst was stable during the reaction, its catalytic properties were little changed after being reused 4 times.</p></div>\",\"PeriodicalId\":20864,\"journal\":{\"name\":\"Reactive Polymers\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1995-02-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/0923-1137(94)00090-R\",\"citationCount\":\"4\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Reactive Polymers\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/092311379400090R\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Reactive Polymers","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/092311379400090R","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Selective hydrogenation of anisol to cyclohexyl methyl ether catalyzed by a silica-supported carboxymethyl cellulose-platinum complex under mild reaction conditions
Selective hydrogenation of anisol to cyclohexyl methyl ether in 100% yield has been achieved by a new natural polymer catalyst, silica-supported carboxymethyl cellulose-platinum complex (SiO2CMCPt) at 30°C and 1 atm mild reaction conditions. The ratio, temperature and solvent had great influence on the reaction. The catalyst was stable during the reaction, its catalytic properties were little changed after being reused 4 times.
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