NCO/OH比和反应稀释剂类型对甲基丙烯酸聚氨酯胶帘/橡胶复合材料粘接强度的影响

Q2 Materials Science

Polymer-Plastics Technology and Engineering Pub Date : 2018-07-03 DOI:10.1080/03602559.2017.1364382

Z. Yildiz, Hacer Aysen Onen, A. Gungor, Youjiang Wang, K. Jacob

{"title":"NCO/OH比和反应稀释剂类型对甲基丙烯酸聚氨酯胶帘/橡胶复合材料粘接强度的影响","authors":"Z. Yildiz, Hacer Aysen Onen, A. Gungor, Youjiang Wang, K. Jacob","doi":"10.1080/03602559.2017.1364382","DOIUrl":null,"url":null,"abstract":"ABSTRACT A series of dual curable polyurethane methacrylate-based oligomers were synthesized by changing the NCO:OH ratio and then were included in adhesive formulations using trimethylolpropane trimethacrylate and tricyclodecane dimethanol diacrylate (TCDDA) as reactive diluents. The effects of NCO:OH ratio and reactive diluent type on the structural properties of UV-cured free films and adhesion properties between polyester cord/rubber surfaces were studied. The highest adhesion strength of the 103 N cm−1 was obtained when the NCO:OH ratio was set as 4 and the TCDDA was used as a reactive diluent. GRAPHICAL ABSTRACT","PeriodicalId":20629,"journal":{"name":"Polymer-Plastics Technology and Engineering","volume":"105 1","pages":"935 - 944"},"PeriodicalIF":0.0000,"publicationDate":"2018-07-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"8","resultStr":"{\"title\":\"Effects of NCO/OH Ratio and Reactive Diluent Type on the Adhesion Strength of Polyurethane Methacrylates for Cord/Rubber Composites\",\"authors\":\"Z. Yildiz, Hacer Aysen Onen, A. Gungor, Youjiang Wang, K. Jacob\",\"doi\":\"10.1080/03602559.2017.1364382\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"ABSTRACT A series of dual curable polyurethane methacrylate-based oligomers were synthesized by changing the NCO:OH ratio and then were included in adhesive formulations using trimethylolpropane trimethacrylate and tricyclodecane dimethanol diacrylate (TCDDA) as reactive diluents. The effects of NCO:OH ratio and reactive diluent type on the structural properties of UV-cured free films and adhesion properties between polyester cord/rubber surfaces were studied. The highest adhesion strength of the 103 N cm−1 was obtained when the NCO:OH ratio was set as 4 and the TCDDA was used as a reactive diluent. GRAPHICAL ABSTRACT\",\"PeriodicalId\":20629,\"journal\":{\"name\":\"Polymer-Plastics Technology and Engineering\",\"volume\":\"105 1\",\"pages\":\"935 - 944\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2018-07-03\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"8\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Polymer-Plastics Technology and Engineering\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1080/03602559.2017.1364382\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"Materials Science\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Polymer-Plastics Technology and Engineering","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1080/03602559.2017.1364382","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"Materials Science","Score":null,"Total":0}

引用次数: 8

摘要

摘要通过改变NCO:OH的比例合成了一系列可双固化的聚氨酯甲基丙烯酸酯基低聚物，并以三甲基丙烯酸三甲基丙烷和三环癸烷二甲醇二丙烯酸酯(TCDDA)为反应稀释剂加入胶粘剂配方中。研究了NCO:OH比和反应稀释剂类型对紫外光固化自由膜结构性能和聚酯帘子/橡胶表面粘附性能的影响。当NCO:OH比为4时，以TCDDA作为反应稀释剂，得到了103 N cm−1的最高粘附强度。图形抽象

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文本刊更多论文

Effects of NCO/OH Ratio and Reactive Diluent Type on the Adhesion Strength of Polyurethane Methacrylates for Cord/Rubber Composites

ABSTRACT A series of dual curable polyurethane methacrylate-based oligomers were synthesized by changing the NCO:OH ratio and then were included in adhesive formulations using trimethylolpropane trimethacrylate and tricyclodecane dimethanol diacrylate (TCDDA) as reactive diluents. The effects of NCO:OH ratio and reactive diluent type on the structural properties of UV-cured free films and adhesion properties between polyester cord/rubber surfaces were studied. The highest adhesion strength of the 103 N cm−1 was obtained when the NCO:OH ratio was set as 4 and the TCDDA was used as a reactive diluent. GRAPHICAL ABSTRACT

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Polymer-Plastics Technology and Engineering 工程技术-高分子科学

CiteScore

1.71

自引率

0.00%

发文量

审稿时长

4 months