{"title":"低自旋铁(III)膦酸盐配合物电子结构的核磁共振研究:异常(dxz, dyz)4(dxy)1构型","authors":"M. Guillemot, G. Simonneaux","doi":"10.1039/C39950002093","DOIUrl":null,"url":null,"abstract":"Complexation of dimethylphenylphosphonite to (5,10,15,20-tetraphenylporphyrinato)iron(III) yields a low-spin derivative [Fe(tpp){P(OMe)2Ph}2]ClO4, showing NMR and EPR properties consistent with an iron(III) ion in the unusual ground-state configuration(dxy,dyz)4(dxy)1.","PeriodicalId":17282,"journal":{"name":"Journal of The Chemical Society, Chemical Communications","volume":"12 1","pages":"2093-2094"},"PeriodicalIF":0.0000,"publicationDate":"1995-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"6","resultStr":"{\"title\":\"NMR studies of the electronic structure of low-spin iron(III) phosphonite complexes: unusual (dxz, dyz)4(dxy)1 configuration\",\"authors\":\"M. Guillemot, G. Simonneaux\",\"doi\":\"10.1039/C39950002093\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Complexation of dimethylphenylphosphonite to (5,10,15,20-tetraphenylporphyrinato)iron(III) yields a low-spin derivative [Fe(tpp){P(OMe)2Ph}2]ClO4, showing NMR and EPR properties consistent with an iron(III) ion in the unusual ground-state configuration(dxy,dyz)4(dxy)1.\",\"PeriodicalId\":17282,\"journal\":{\"name\":\"Journal of The Chemical Society, Chemical Communications\",\"volume\":\"12 1\",\"pages\":\"2093-2094\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1995-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"6\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Chemical Society, Chemical Communications\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/C39950002093\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society, Chemical Communications","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/C39950002093","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
NMR studies of the electronic structure of low-spin iron(III) phosphonite complexes: unusual (dxz, dyz)4(dxy)1 configuration
Complexation of dimethylphenylphosphonite to (5,10,15,20-tetraphenylporphyrinato)iron(III) yields a low-spin derivative [Fe(tpp){P(OMe)2Ph}2]ClO4, showing NMR and EPR properties consistent with an iron(III) ion in the unusual ground-state configuration(dxy,dyz)4(dxy)1.
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