土耳其伊斯坦布尔对dl-多氯联苯和PCDD/F化合物大气浓度的评价

G. Gunes, A. Saral
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引用次数: 3

摘要

本研究探讨了大气PCDD/F和Dl-PCB浓度的季节变化及气象因子对浓度的影响。2011年5月至2013年10月,采用大容量采样器每月采集环境空气样本。根据这些样品,PCDD/F和dl-PCB的平均浓度分别为1482 fg/m3和4983 fg/m3。PCDD/F同系物确实表现出季节变化。冬季占总PCDD/Fs的58%,夏季占4%。二氯联苯未观察到明显的季节变化。PCDD/Fs中有92% (1397 fg/m3)存在于颗粒相,dl-PCBs中有20% (926 fg/m3)存在于颗粒相。所有同源基团与T、UV、SR呈显著负相关,而被抛弃最多的五氯代dl- pcb与T、UV、SR呈显著正相关。与其他参数无显著相关性。与气相相比,PCDD/Fs和dl- pcb与颗粒相的相关性更有意义。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Evaluation of atmospheric concentrations of dl-PCBs comparing to PCDD/F compounds in Istanbul, Turkey
In this study, the seasonal variation of atmospheric concentrations of PCDD/F and Dl-PCB and the effect of meteorological factors on concentration were investigated. Ambient air samples were collected monthly between May 2011 and October 2013 by using high volume samplers. Based on these samples, average PCDD/F and dl-PCB concentrations were obtained as 1482 fg/m3 and 4983 fg/m3 respectively. PCDD/F congeners did show seasonal variations. 58% share in total PCDD/Fs belongs to winter season while 4% to summer season. No significant seasonal change has been observed for dl-PCBs. 92% (1397 fg/m3) of PCDD/Fs were detected in particulate phase while 20% (926 fg/m3) of dl-PCBs were found in particulate phase. Strong negative correlations were obtained between all homolog groups and T, UV, SR. Correlation between five-chlorinated dl-PCBs, the most abandoned homolog group, with T, UV and SR generated positive meaningful correlation. No meaningful correlations were observed with other parameters. Correlations with particle phase were found to be more meaningful compared to gas phase for both PCDD/Fs and dl-PCBs.
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