在液-液界面处液滴的形状。一、两相理论的推广与检验

H.M Princen, S.G Mason
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引用次数: 66

摘要

通过测量气-水界面稳定气泡的特征尺寸,证实了两相系统中液-液界面处液滴形状的理论。气泡顶部的平衡膜可以同时由两种不同厚度的膜组成。讨论了产生这种情况的条件及其对膜对气体渗透性的影响。当平衡膜的张力小于正常表面张力的两倍时,就会发生与形状理论的偏差。已经进行了计算,将理论扩展到具有这种薄膜张力降低的系统。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Shape of a fluid drop at a fluid-liquid interface. I. Extension and test of two-phase theory

The theory of the shape of a fluid drop at a fluid-liquid interface in two-phase systems was confirmed experimentally by measuring characteristic dimensions of stabilized air bubbles at an air-water interface.

The equilibrium film at the top of the bubble may simultaneously consist of two types of film of different thickness. The condition for this situation and its effect on the permeability of the film to gases is discussed.

Deviations from the shape theory will occur when the tension of the equilibrium film is smaller than twice the normal surface tension. Calculations have been made to extend the theory to systems with such a reduced film tension.

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