低温臭氧分解反应中卤化物离子对天然膨润土负载d -金属配合物活性的影响

IF 0.5 Q4 CHEMISTRY, MULTIDISCIPLINARY

Chemistry Journal of Moldova Pub Date : 2022-06-01 DOI:10.19261/cjm.2021.912

T. Rakitskaya, A. Truba, G. Dzhyga

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引用次数: 0

摘要

研究了卤化物离子(X= Cl−，Br−，I−)对乌克兰达舒科夫斯克矿床天然膨润土(N-Bent(D))负载成分分解臭氧动力学的影响。结果表明，臭氧分解反应中KX/N-Bent(D)组分的活性在KCl << KBr < KI行中增加，这与它们的还原性能增加有关(Х2/2Х−对的氧化还原电位降低)。该催化剂组合物可推荐用于呼吸系统的个人防护设备。

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The Effect of Halide Ions on the Activity of D-metal Complexes Supported on Natural Bentonite in the Reaction of Low Temperature Ozone Decomposition

The effect of halide ions (X= Cl−, Br−, I−) on the kinetics of ozone decomposition by compositions supported on the natural bentonite of the Dashukovske deposit in Ukraine (N-Bent(D)) has been studied. The obtained results have shown that the activity of the KX/N-Bent(D) composition in the ozone decomposition reaction increases in the row KCl << KBr < KI, which correlates with an increase in their reducing properties (the redox potential of the Х2/2Х− pair decreases). Such catalyst compositions can be recommended for applying in personal protective equipment for the respiratory system.

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来源期刊

Chemistry Journal of Moldova CHEMISTRY, MULTIDISCIPLINARY-

CiteScore

0.90

自引率

20.00%

发文量

审稿时长

12 weeks

期刊介绍： "Chemistry Journal of Moldova. General, Industrial and Ecological Chemistry" seeks to publish experimental or theoretical research results of outstanding significance and timeliness in all fields of Chemistry, including Industrial and Ecological Chemistry. The main goal of this edition is strengthening the Chemical Society of Moldova, following development of research in Moldovan chemical institutions and promotion of their collaboration with international chemical community. Manuscripts are welcome from all countries.