298.15 K温度下环戊基甲基醚与氯苯和环戊基甲基醚与丙烯酸甲酯二元液体混合物的物理化学和声学性能比较研究

Sonu Dwivedi
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引用次数: 0

摘要

液体混合物的物理化学和声学特性为研究液体的行为和相互作用提供了知识。超声波在液体和溶液中的研究提供了一些关于这些系统的结构和相互作用的有价值的信息。超声声速和密度已被证明是检验液态模型有效性的重要性质。在298.15 K温度下,用纯组分测定了氯苯(极性)+环戊基甲基醚(非极性)[体系一]和丙烯酸甲酯(极性)+环戊基甲基醚(非极性)[体系二]二元液体混合物的超声速度(U)和密度(ρ)。利用这些测量的特性,利用标准关系式计算了多余的声学参数。利用多组分液体混合物中多余的声学参数进行定性和定量分析。多余参数的符号和大小提供了不同类型相互作用的信息。结构化学与液体系统中的相互作用有关。结构效应也决定了液体混合系统I和II的性质和结合。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Comparative Study of Physicochemical and Acoustic Properties of Binary Liquid Mixtures of Cyclopentyl Methyl Ether with Chlorobenzene and Cyclopentyl Methyl Ether with Methyl Acrylate at 298.15 K Temperature
Physicochemical and acoustic propertie of liquid mixtures give knowlegeble information behaviour and interactions studies of liquids. Ultrasonic studies in liquids and solutions provide some valuable information about the structure and interaction in such systems. Ultrasonic velocity and density have been proved to be important properties to test the validity of liquid state model. The ultrasonic velocity (U) and density (ρ) of the binary liquid mixtures Chlorobenzene (polar)+Cyclopentyl methyl ether (nonpolar) [system I] and Methyl acrylate (polar) +Cyclopentyl methyl ether (nonpolar) [system II] are measured at 298.15 K temp. with pure components. With the help of these measured properties are calculated excess acoustic parameters using standard relations. Excess acoustic parameters are used as a qualitative and quantitative analysis in multicomponent liquid mixtures. The sign and magnitude of excess parameters provided information of different type interactions. Structural chemistry is related to the interactions involved in the liquid systems. structural effects also define nature and bonding of both liquid mixture system I and II.
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