催化剂负载介质阻挡放电反应器的表征

Yao Shui-liang, Yamamoto Shin, Kodama Satoshi, Mineo Chieko, F. Yuichi
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引用次数: 10

摘要

研究了Fe2O3和TiO2催化剂层负载的介质(氧化铝Al2O3)阻挡放电(DBD)反应器在等离子体放电中的放电特性和化学反应。臭氧(O3)作为探测物质监测等离子体放电驱动的化学反应。利用配备高动态范围条纹相机的单色仪,对等离子体放电引起的催化剂支撑DBD反应器放电间隙的光发射进行了评估。研究发现,Fe2O3和TiO2的催化剂层对等离子体放电和O3的生成没有明显影响。催化剂负载的DBD反应器放电间隙的光发射不同,可能是由于催化剂层对光的吸收和散射不同。提出了Fe2O3层对PM氧化脱除的催化作用机理,其中Fe2O3层的光吸收效果比TiO2和Al2O3层的光吸收效果最好。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Characterization of Catalyst-Supported Dielectric Barrier Discharge Reactor
The discharge properties and chemical reactions in plasma discharges using dielectric (alumina Al2O3) barrier discharge (DBD) reactors supported with Fe2O3 and TiO2 catalyst layers have been characterized. Ozone (O3) was used as a probe substance to monitor the chemical reactions driven by plasma discharges. The light emission from discharge gaps of the catalyst-supported DBD reactors due to plasma discharges was evaluated, using a monochromator equipped with a high dynamic range streak camera. It has been found that the catalyst layers of Fe2O3 and TiO2 do not obviously influence plasma discharges and O3 generation. Light emission from the discharge gaps of the catalyst-supported DBD reactors is different possibly due to the difference in light absorption and scattering by catalyst layers. The mechanism of catalysis effect on PM oxidative removal over Fe2O3 has been proposed, where Fe2O3 layer has the highest light absorption effect compared with that of TiO2 and Al2O3.
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