NaMgAl(草酸盐)3·9H2O∶Cr(III)晶体2E←4A2跃迁的非光化学光谱烧孔

PhysChemComm Pub Date : 2001-01-01 DOI:10.1039/B110096C

M. L. Lewis, H. Riesen

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摘要

报道了晶体NaMgAl(草酸盐)3·9 h2o∶Cr(III)在2 E←4 a2跃迁过程中的非光化学光谱烧洞及其温度依赖性，并提出了烧洞机理。本文首次报道了晶体中铬(III)在2 E←4 a2跃迁过程中的非光化学烧孔现象。

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Non-photochemical spectral hole-burning in the 2E←4A2 transition of crystalline NaMgAl(oxalate)3·9H2O∶Cr(III)

Non-photochemical spectral hole-burning in the 2 E← 4 A 2 transition of crystalline NaMgAl(oxalate) 3 ·9H 2 O∶Cr(III) and its temperature dependence is reported and a hole-burning mechanism is proposed. This is the first report of non-photochemical hole-burning in the 2 E← 4 A 2 transition of chromium(III) in a crystal.

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PhysChemComm

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