高分子[M(Quin)2(N(CN)2)2]∞(M = Mn(II)， Co(II))的合成、结构、磁性和抗菌性能喹啉)

IF 0.5 Q4 MULTIDISCIPLINARY SCIENCES

Journal of Mathematical and Fundamental Sciences Pub Date : 2023-03-19 DOI:10.5614/j.math.fund.sci.2022.54.2.4

Wayan Dasna, Ubed Sonai, Fahruddin Arrozi, H. W. Wijaya, Sutandyo Dwija Laksmana, S. Golhen

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引用次数: 0

摘要

合成并表征了[Mn(Quin)2(N(CN)2)2]∞(1)和[Co(Quin)2(N(CN)2)2]∞(2)两个配合物。合成的配合物结晶为三斜晶格，空间群为P-1。的晶胞参数1 = 7.5207 (14),b = 7.7729 (16), c = 9.5968(15),α= 96.388 (6)o,β= 112.617 (5)o,γ= 102.751 (6)o,而对于复杂2 = 7.3942 (10),b = 7.7960 (10) a, c = 9.4907(13),α= 96.631 (4)o,β= 112.742 (4)o,γ= 102.458 (4)o。磁性性能和抗菌性能的高分子复合物被磁化率和扩散技术检查,分别。配合物1和2均表现出反铁磁性，对金黄色葡萄球菌生长的抑制作用高于伤寒沙门氏菌。

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Synthesis, Structure, Magnetic and Antibacterial Properties of polymeric [M(Quin)2(N(CN)2)2]∞ (M = Mn(II), Co(II); Quin = quinoline)

Two complexes of [Mn(Quin)2(N(CN)2)2]∞ (1) and [Co(Quin)2(N(CN)2)2]∞ (2) were synthesized and characterized. The as-synthesized complexes crystallized in a triclinic lattice with a space group of P-1. The unit cell parameter of 1 was a = 7.5207(14) Å, b = 7.7729(16) Å, c = 9.5968(15) Å, α = 96.388(6) o, β = 112.617(5) o, γ = 102.751(6) o, while for complex 2 it was a = 7.3942(10) Å, b = 7.7960(10) Å, c = 9.4907(13) Å, α = 96.631(4) o, β = 112.742(4) o, γ = 102.458(4) o. The magnetic properties and antimicrobial properties of both polymeric complexes were examined by magnetic susceptibility and diffusion techniques, respectively. Complexes 1 and 2 both showed antiferromagnetic properties and had a higher inhibitory effect on the growth of Staphylococcus aureus than Salmonella typhi.

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来源期刊

Journal of Mathematical and Fundamental Sciences MULTIDISCIPLINARY SCIENCES-

CiteScore

1.30

自引率

0.00%

发文量

审稿时长

24 weeks

期刊介绍： Journal of Mathematical and Fundamental Sciences welcomes full research articles in the area of Mathematics and Natural Sciences from the following subject areas: Astronomy, Chemistry, Earth Sciences (Geodesy, Geology, Geophysics, Oceanography, Meteorology), Life Sciences (Agriculture, Biochemistry, Biology, Health Sciences, Medical Sciences, Pharmacy), Mathematics, Physics, and Statistics. New submissions of mathematics articles starting in January 2020 are required to focus on applied mathematics with real relevance to the field of natural sciences. Authors are invited to submit articles that have not been published previously and are not under consideration elsewhere.