{"title":"由分子氮生成阳离子双核铁二氮化合物","authors":"W. Silverthorn","doi":"10.1039/C29710001310","DOIUrl":null,"url":null,"abstract":"Treatment of the compound π-C5H5Fe(dmpe)I (dmpe = Me2PCH2CH2PMe2) in acetone with TlBF4 and nitrogen gas yields the binuclear dinitrogen complex {[π–C5H5Fe(dmpe)]2N2}2+(BF4–)2, 2H2O which readily reacts with carbon monoxide and LiAlH4 giving the complexes [π–C5H5Fe(dmpe)CO]+BF4– and π–C5H5Fe(dmpe)H, respectively.","PeriodicalId":17278,"journal":{"name":"Journal of The Chemical Society D: Chemical Communications","volume":"114 1","pages":"1310-1311"},"PeriodicalIF":0.0000,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"20","resultStr":"{\"title\":\"Formation of a cationic binuclear iron–dinitrogen compound from molecular nitrogen\",\"authors\":\"W. Silverthorn\",\"doi\":\"10.1039/C29710001310\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Treatment of the compound π-C5H5Fe(dmpe)I (dmpe = Me2PCH2CH2PMe2) in acetone with TlBF4 and nitrogen gas yields the binuclear dinitrogen complex {[π–C5H5Fe(dmpe)]2N2}2+(BF4–)2, 2H2O which readily reacts with carbon monoxide and LiAlH4 giving the complexes [π–C5H5Fe(dmpe)CO]+BF4– and π–C5H5Fe(dmpe)H, respectively.\",\"PeriodicalId\":17278,\"journal\":{\"name\":\"Journal of The Chemical Society D: Chemical Communications\",\"volume\":\"114 1\",\"pages\":\"1310-1311\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1971-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"20\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Chemical Society D: Chemical Communications\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/C29710001310\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society D: Chemical Communications","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/C29710001310","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Formation of a cationic binuclear iron–dinitrogen compound from molecular nitrogen
Treatment of the compound π-C5H5Fe(dmpe)I (dmpe = Me2PCH2CH2PMe2) in acetone with TlBF4 and nitrogen gas yields the binuclear dinitrogen complex {[π–C5H5Fe(dmpe)]2N2}2+(BF4–)2, 2H2O which readily reacts with carbon monoxide and LiAlH4 giving the complexes [π–C5H5Fe(dmpe)CO]+BF4– and π–C5H5Fe(dmpe)H, respectively.
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