{"title":"[(π-C5H5)Fe(CO)2]2二叔膦桥接衍生物的可逆氧化反应","authors":"J. Ferguson, T. Meyer","doi":"10.1039/C29710001544","DOIUrl":null,"url":null,"abstract":"The carbonyl–diphosphine bridged dimer [(π-C5H5)Fe(CO)]2[Ph2P(CH2)3PPh2]{Fe2(diphos)} is reversibly oxidized electrochemically to the cation Fe2(diphos)+ which disproportionates in acetonitrile and is further oxidized to the transient dication Fe2(diphos)2+.","PeriodicalId":17278,"journal":{"name":"Journal of The Chemical Society D: Chemical Communications","volume":"16 1","pages":"1544-1545"},"PeriodicalIF":0.0000,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"5","resultStr":"{\"title\":\"Reversible oxidations in ditertiary-phosphine bridged derivatives of [(π-C5H5)Fe(CO)2]2\",\"authors\":\"J. Ferguson, T. Meyer\",\"doi\":\"10.1039/C29710001544\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The carbonyl–diphosphine bridged dimer [(π-C5H5)Fe(CO)]2[Ph2P(CH2)3PPh2]{Fe2(diphos)} is reversibly oxidized electrochemically to the cation Fe2(diphos)+ which disproportionates in acetonitrile and is further oxidized to the transient dication Fe2(diphos)2+.\",\"PeriodicalId\":17278,\"journal\":{\"name\":\"Journal of The Chemical Society D: Chemical Communications\",\"volume\":\"16 1\",\"pages\":\"1544-1545\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1971-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"5\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Chemical Society D: Chemical Communications\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/C29710001544\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society D: Chemical Communications","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/C29710001544","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Reversible oxidations in ditertiary-phosphine bridged derivatives of [(π-C5H5)Fe(CO)2]2
The carbonyl–diphosphine bridged dimer [(π-C5H5)Fe(CO)]2[Ph2P(CH2)3PPh2]{Fe2(diphos)} is reversibly oxidized electrochemically to the cation Fe2(diphos)+ which disproportionates in acetonitrile and is further oxidized to the transient dication Fe2(diphos)2+.
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