第二族元素硫酸盐过氧化物的合成与研究

A. I. Martiryan, L. Tadevosyan
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引用次数: 0

摘要

在前人类似研究的基础上,对第二族元素——镁、钙和锌的硫酸盐生成过溶剂化物的能力、制备方法以及性质进行了研究。结果表明,这些硫酸盐能够生成不同摩尔比的过溶剂化物:MgSO4·H2O2、CaSO4·0.04H2O2、ZnSO4·0.05H2O2。用x射线和红外光谱方法对所得过溶剂化物的真实性、组成和性质进行了鉴定。计算了过氧化氢在干燥的硫酸镁和硫酸锌过氧化物中分解的定量数据。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
SYNTHESIS AND STUDY OF PEROXOSOLVATES OF SULFATES OF ELEMENTS OF THE SECOND GROUP
Continuing previous similar research, the ability of sulfates of elements of the second group – magnesium, calcium and zinc, to produce peroxosolvates, the methods for their preparation, as well as their properties have been studied. It has been shown that these sulfates are able to produce peroxosolvates with different molar ratios: MgSO4‧H2O2, CaSO4‧0.04H2O2, ZnSO4‧0.05H2O2. The authenticity, composition and nature of the obtained peroxosolvates have been elucidated by the methods of X-ray and IR spectroscopy. Quantitative data on the decomposition of hydrogen peroxide in dry peroxosolvates of magnesium and zinc sulfates were calculated.
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