{"title":"4-烷基氧羰基- n -羟基邻苯二胺催化异丙苯的好氧氧化","authors":"Kornela Kasperczyk, Beata Orlińska, J. Zawadiak","doi":"10.2478/s11532-014-0565-8","DOIUrl":null,"url":null,"abstract":"Abstract4-Hexyloxycarbonyl-, 4-dodecyloxycarbonyl- and 4-hexadecyloxycarbonyl-N-hydroxyphthalimides were synthesised using trimellitic anhydride chloride as the starting material. The obtained lipophilic derivatives of N-hydroxyphthalimide were applied as catalysts of the cumene oxidation reaction with oxygen performed in polar acetonitrile, in non-polar tert-butylbenzene and in the absence of a solvent. The courses of reactions catalysed by N-hydroxyphthalimide and its derivatives were compared.\n","PeriodicalId":9888,"journal":{"name":"Central European Journal of Chemistry","volume":"51 1","pages":"1176-1182"},"PeriodicalIF":0.0000,"publicationDate":"2014-05-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"39","resultStr":"{\"title\":\"Aerobic oxidation of cumene catalysed by 4-alkyloxycarbonyl-N-hydroxyphthalimide\",\"authors\":\"Kornela Kasperczyk, Beata Orlińska, J. Zawadiak\",\"doi\":\"10.2478/s11532-014-0565-8\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Abstract4-Hexyloxycarbonyl-, 4-dodecyloxycarbonyl- and 4-hexadecyloxycarbonyl-N-hydroxyphthalimides were synthesised using trimellitic anhydride chloride as the starting material. The obtained lipophilic derivatives of N-hydroxyphthalimide were applied as catalysts of the cumene oxidation reaction with oxygen performed in polar acetonitrile, in non-polar tert-butylbenzene and in the absence of a solvent. The courses of reactions catalysed by N-hydroxyphthalimide and its derivatives were compared.\\n\",\"PeriodicalId\":9888,\"journal\":{\"name\":\"Central European Journal of Chemistry\",\"volume\":\"51 1\",\"pages\":\"1176-1182\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2014-05-06\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"39\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Central European Journal of Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.2478/s11532-014-0565-8\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Central European Journal of Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.2478/s11532-014-0565-8","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 39
摘要
摘要以氯偏苯三酸酐为原料合成了4-己基氧羰基-、4-十二烷基氧羰基-和4-十六烷基氧羰基- n -羟基邻苯酞酰亚胺。得到的n-羟基邻苯亚胺亲脂衍生物作为催化剂，在极性乙腈、非极性叔丁基苯和无溶剂条件下进行了异丙烯的氧氧化反应。比较了n -羟基邻苯二胺及其衍生物催化反应的过程。
Aerobic oxidation of cumene catalysed by 4-alkyloxycarbonyl-N-hydroxyphthalimide
Abstract4-Hexyloxycarbonyl-, 4-dodecyloxycarbonyl- and 4-hexadecyloxycarbonyl-N-hydroxyphthalimides were synthesised using trimellitic anhydride chloride as the starting material. The obtained lipophilic derivatives of N-hydroxyphthalimide were applied as catalysts of the cumene oxidation reaction with oxygen performed in polar acetonitrile, in non-polar tert-butylbenzene and in the absence of a solvent. The courses of reactions catalysed by N-hydroxyphthalimide and its derivatives were compared.
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