烯烃复分解聚合制备不饱和主链金属聚合物的合成策略、性能及应用

IF 11.1 2区化学 Q1 POLYMER SCIENCE

Polymer Reviews Pub Date : 2020-08-07 DOI:10.1080/15583724.2020.1801727

Ye Sha, H. Jia, Zhihua Shen, Zhenyang Luo

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引用次数: 8

摘要

摘要采用烯烃复分解聚合法合成了主链金属聚合物。这些聚合物主要通过无环二烯复合聚合(ADMET)和开环复合聚合(ROMP)制备。特殊的金属基团、金属结合基序和不饱和大分子骨架赋予了金属聚合物独特的性能。本文综述了近年来烯烃复分解聚合带主基和过渡金属的主链金属聚合物的研究进展。我们着重介绍了这些聚合物的合成、理化性质和应用。从单体构效关系和聚合效率的角度讨论了合成策略。在刺激响应性、电导率和晶体特性方面，强调了大分子组成/序列与新兴特性之间的相关性。最后，介绍了该领域的现状，并指出了未来研究的灰色地带。

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Synthetic strategies, properties, and applications of unsaturated main-chain metallopolymers prepared by olefin metathesis polymerization

Abstract Main-chain metallopolymers are synthesized by olefin metathesis polymerizations. These polymers are mainly produced through acyclic diene metathesis (ADMET) polymerization and ring-opening metathesis polymerization (ROMP). The special metal moieties, metal-binding motifs, and unsaturated macromolecular backbone endow the metallopolymers with unique properties. This review highlights recent advances in studies on the family of main-chain metallopolymers carrying both main-group and transition metals by olefin metathesis polymerizations. We emphasize the synthesis, physiochemical properties, and applications of these polymers. Synthetic strategies are discussed from a perspective of the structure-activity relationship between monomers and polymerization efficiency. The correlations between macromolecular compositions/sequences and emerging properties are highlighted in terms of stimuli-responsiveness, conductivity, and crystalline characteristics. Lastly, we describe the current status of the field and highlight gray areas for future research.

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来源期刊

Polymer Reviews 工程技术-高分子科学

CiteScore

24.80

自引率

0.80%

发文量

审稿时长

6 months

期刊介绍： Polymer Reviews is a reputable publication that focuses on timely issues within the field of macromolecular science and engineering. The journal features high-quality reviews that have been specifically curated by experts in the field. Topics of particular importance include biomedical applications, organic electronics and photonics, nanostructures, micro- and nano-fabrication, biological molecules (such as DNA, proteins, and carbohydrates), polymers for renewable energy and environmental applications, and interdisciplinary intersections involving polymers. The articles in Polymer Reviews fall into two main categories. Some articles offer comprehensive and expansive overviews of a particular subject, while others zero in on the author's own research and situate it within the broader scientific landscape. In both types of articles, the aim is to provide readers with valuable insights and advancements in the field of macromolecular science and engineering.