获得基于二次聚丙烯和聚对苯二甲酸乙二醇酯的防腐组合物

A.Sh. Kydyraliyeva, O. K. Beissenbayev, K. Nadirov, Ye.A. Tussupkaliyev
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摘要

本文介绍了为保护储油罐底部不受腐蚀而研制新型防腐成分的问题。结果表明,国内现有的生产防腐涂料的材料尚未广泛应用于石油生产和储存设施设备的防腐。解决这一问题的途径之一是开发基于二次聚合物和一些天然树脂的新型防腐组合物。提出了一种新型储油罐底部防腐复合材料的组成。通过在实验室多功能挤出机中混合各组分得到聚合物组合物。基于光谱研究,对复合材料的结构进行了分析,认为在挤出机中最可能发生的化学过程是醋酸乙烯与棉酚及其衍生物以及棉酚树脂中游离脂肪酸分子的相互作用。所获得的罐体金属底部金属表面腐蚀产物的显微图像让我们可以陈述,在这些条件下,发生点蚀,针的穿透深度为4-6毫米/年。在复合材料的组成中加入棉酚树脂和萨维木,促进了氧化降解过程的抑制速率,并且另外增加了对金属表面的粘附力10-15%。所制得的以七苯乙烯、二次聚丙烯、聚对苯二甲酸乙二醇酯和棉酚树脂为基础的聚合物防腐组合物是一种有效的防腐涂料,可用于储油罐底部的防腐。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
OBTAINING ANTI-CORROSION COMPOSITIONS BASED ON SECONDARY POLYPROPYLENE AND POLYETHYLENE TEREPHTHALATE
In the article, the issues of obtaining new anti-corrosion compositions for protecting the bottom of oil storage tanks from corrosion. It is shown that the available domestic materials for the production of anti-corrosion protective coatings have not yet been widely used to protect the equipment of oil production and storage facilities from corrosion. One of the ways to solve this problem is the development of new anti-corrosion compositions based on secondary polymers and some natural resins. The composition of a new composite material for corrosion protection of the bottom of oil storage tanks is proposed. Polymer compositions were obtained by mixing the components in a laboratory multifunctional extruder. Based on spectral studies, a conclusion was made about the structure of the composite, it was shown that the most probable chemical processes occurring in the extruder are the interaction of vinyl acetate with gossypol, its derivatives, as well as molecules of free fatty acids of gossypol resin. The obtained microscopic images of corrosion products on the metal surface of the bottom of the metal of the tank allow us to state that under these conditions, pitting corrosion occurs, the penetration depth of the needle is 4–6 mm/year. The addition of gossypol resin and savilen to the composition of the composite promotes inhibition of the rate of the oxidative degradation process, and additionally increases adhesion to the metal surface by 10-15%. The resulting composition of polymeric anticorrosion compositions based on sevilen, secondary polypropylene, crushed polyethylene terephthalate and gossypol resin is an effective anticorrosion coating and can be used to protect the bottom of oil storage tanks from corrosion.
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