新型Ba(II)掺杂Cd(II)配位聚合物的合成、结构及光致发光性能

Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Pub Date : 2016-05-03 DOI:10.1080/15533174.2014.989587

Pingping Zhou, Xiaohui Li, Yanli Dong, Hui-min Liu

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引用次数: 1

摘要

采用溶剂热法合成了一种新的杂金属化合物[CdBa(tdc)2(DMF)2(H2O)]n (1 H2tdc = 2,5-噻吩二羧酸，DMF = n, n ' -二甲基甲酰胺)，并用元素分析和x射线单晶衍射对其进行了表征。化合物1具有基于杂金属-{Cd-COO-Ba}n-无机链的复杂三维(3D)结构。此外，还研究了该化合物在室温下的发光性能。

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Synthesis, Structure and Photoluminescent Properties of a New Ba(II)-Doped Cd(II) Coordination Polymer

A new heterometallic compound, namely [CdBa(tdc)2(DMF)2(H2O)]n (1 H2tdc = 2,5-thiophenedicarboxylic acid, DMF = N,N′-dimethylformamide), has been solvothermally synthesized and characterized by elemental analysis and single crystal X-ray diffraction. Compound 1 features a complicated three-dimensional (3D) framework based on heterometallic -{Cd-COO-Ba}n- inorganic chains. In addition, the luminescent properties of this compound were also investigated at room temperature.

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来源期刊

Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry 工程技术-纳米科技

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审稿时长

5 months