R. Kruszyński, Tomasz Sierański, Bartłomiej Lewiński, A. Trzesowska-Kruszynska, Ewelina Czubacka
{"title":"双(3,5,7-三氮杂-1-氮杂三环[]十烷)双(-氧)-三(-氧)-非akis(-氧)-非水-十氧-七-钼-二锌(II)二水合物的合成及性质","authors":"R. Kruszyński, Tomasz Sierański, Bartłomiej Lewiński, A. Trzesowska-Kruszynska, Ewelina Czubacka","doi":"10.1155/2012/516832","DOIUrl":null,"url":null,"abstract":"The reaction of molybdophosphoric acid with zinc carbonate followed by addition of hmta leads to formation of a triclinic polymorph of bis(3,5,7-triaza-1-azoniatricyclo[]decane) bis(-oxo)-tris(-oxo)-nonakis(-oxo)-nonaaqua-decaoxo-hepta-molybdenum-di-zinc(II) dihydrate in a one pot simple reaction. The obtained compound has been characterised by IR, UV-Vis spectroscopy, elemental analysis, and X-ray crystallography. A detailed comparison between both polymorphic forms: triclinic A, A, A, , , , and A3 and monoclinic A, A, A, , , , and A3 was performed. The influence of the synthesis procedure on polymorph formation was described.","PeriodicalId":14074,"journal":{"name":"International Journal of Inorganic Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2012-02-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"The Novel Polymorphic Form of Bis(3,5,7-triaza-1-azoniatricyclo[]decane) bis(-oxo)-tris(-oxo)-nonakis(-oxo)-nonaaqua-decaoxo-hepta-molybdenum-di-zinc(II) dihydrate, Synthesis, and Properties\",\"authors\":\"R. Kruszyński, Tomasz Sierański, Bartłomiej Lewiński, A. Trzesowska-Kruszynska, Ewelina Czubacka\",\"doi\":\"10.1155/2012/516832\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The reaction of molybdophosphoric acid with zinc carbonate followed by addition of hmta leads to formation of a triclinic polymorph of bis(3,5,7-triaza-1-azoniatricyclo[]decane) bis(-oxo)-tris(-oxo)-nonakis(-oxo)-nonaaqua-decaoxo-hepta-molybdenum-di-zinc(II) dihydrate in a one pot simple reaction. The obtained compound has been characterised by IR, UV-Vis spectroscopy, elemental analysis, and X-ray crystallography. A detailed comparison between both polymorphic forms: triclinic A, A, A, , , , and A3 and monoclinic A, A, A, , , , and A3 was performed. The influence of the synthesis procedure on polymorph formation was described.\",\"PeriodicalId\":14074,\"journal\":{\"name\":\"International Journal of Inorganic Chemistry\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2012-02-21\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"International Journal of Inorganic Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1155/2012/516832\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Inorganic Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1155/2012/516832","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
The Novel Polymorphic Form of Bis(3,5,7-triaza-1-azoniatricyclo[]decane) bis(-oxo)-tris(-oxo)-nonakis(-oxo)-nonaaqua-decaoxo-hepta-molybdenum-di-zinc(II) dihydrate, Synthesis, and Properties
The reaction of molybdophosphoric acid with zinc carbonate followed by addition of hmta leads to formation of a triclinic polymorph of bis(3,5,7-triaza-1-azoniatricyclo[]decane) bis(-oxo)-tris(-oxo)-nonakis(-oxo)-nonaaqua-decaoxo-hepta-molybdenum-di-zinc(II) dihydrate in a one pot simple reaction. The obtained compound has been characterised by IR, UV-Vis spectroscopy, elemental analysis, and X-ray crystallography. A detailed comparison between both polymorphic forms: triclinic A, A, A, , , , and A3 and monoclinic A, A, A, , , , and A3 was performed. The influence of the synthesis procedure on polymorph formation was described.
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