J.G.H. Du Preez, B.J.A.M. Van Brecht, R.F. Van de Water, M.R. Caira
{"title":"二价钴、镍、铜的配位化学","authors":"J.G.H. Du Preez, B.J.A.M. Van Brecht, R.F. Van de Water, M.R. Caira","doi":"10.1016/0022-1902(81)80538-6","DOIUrl":null,"url":null,"abstract":"<div><p>The preparation, properties and X-ray crystal structure of [Cu(ttda)(tmen)](ClO<sub>4</sub>)<sub>2</sub>, a complex of divalent copper perchlorate with the ligands N,N,N′,N′-tetramethyl-1,2-diaminoethane (tmen) and bis-(N,N′-dimethyl-acetamido)thioether(ttda) are reported. The crystals are monoclinic with <em>a</em> = 15.35(1), <em>b</em> = 15.04(1), <em>c</em> = 10.91(1) A, β = 98.74(2)°, four formula units per unit cell and space group P2<sub>1</sub>/<em>n</em>. The complex cation is shown to be penta-coordinate with a distorted square pyramidal geometry. Comparison is made with the properties and structure of the previously reported CuCl<sub>2</sub>·ttda.</p></div>","PeriodicalId":16275,"journal":{"name":"Journal of Inorganic and Nuclear Chemistry","volume":"43 9","pages":"Pages 2011-2016"},"PeriodicalIF":0.0000,"publicationDate":"1981-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-1902(81)80538-6","citationCount":"4","resultStr":"{\"title\":\"The coordination chemistry of divalent cobalt, nickel and copper—IX\",\"authors\":\"J.G.H. Du Preez, B.J.A.M. Van Brecht, R.F. Van de Water, M.R. Caira\",\"doi\":\"10.1016/0022-1902(81)80538-6\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The preparation, properties and X-ray crystal structure of [Cu(ttda)(tmen)](ClO<sub>4</sub>)<sub>2</sub>, a complex of divalent copper perchlorate with the ligands N,N,N′,N′-tetramethyl-1,2-diaminoethane (tmen) and bis-(N,N′-dimethyl-acetamido)thioether(ttda) are reported. The crystals are monoclinic with <em>a</em> = 15.35(1), <em>b</em> = 15.04(1), <em>c</em> = 10.91(1) A, β = 98.74(2)°, four formula units per unit cell and space group P2<sub>1</sub>/<em>n</em>. The complex cation is shown to be penta-coordinate with a distorted square pyramidal geometry. Comparison is made with the properties and structure of the previously reported CuCl<sub>2</sub>·ttda.</p></div>\",\"PeriodicalId\":16275,\"journal\":{\"name\":\"Journal of Inorganic and Nuclear Chemistry\",\"volume\":\"43 9\",\"pages\":\"Pages 2011-2016\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1981-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/0022-1902(81)80538-6\",\"citationCount\":\"4\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Inorganic and Nuclear Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/0022190281805386\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Inorganic and Nuclear Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0022190281805386","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 4
摘要
报道了二价高氯酸铜与配体N,N,N′，N′-四甲基-1,2-二氨基乙烷(tmen)和双-(N,N′-二甲基-乙酰氨基)硫醚(ttda)的配合物[Cu(ttda)(tmen)](ClO4)2的制备、性能和x射线晶体结构。该晶体为单斜晶，a = 15.35(1)， b = 15.04(1)， c = 10.91(1) a， β = 98.74(2)°，每单元胞有4个公式单元，空间群P21/n。该配合物阳离子显示为五坐标，具有扭曲的方形锥体几何形状。并与文献报道的CuCl2·ttda的性质和结构进行了比较。
The coordination chemistry of divalent cobalt, nickel and copper—IX
The preparation, properties and X-ray crystal structure of [Cu(ttda)(tmen)](ClO4)2, a complex of divalent copper perchlorate with the ligands N,N,N′,N′-tetramethyl-1,2-diaminoethane (tmen) and bis-(N,N′-dimethyl-acetamido)thioether(ttda) are reported. The crystals are monoclinic with a = 15.35(1), b = 15.04(1), c = 10.91(1) A, β = 98.74(2)°, four formula units per unit cell and space group P21/n. The complex cation is shown to be penta-coordinate with a distorted square pyramidal geometry. Comparison is made with the properties and structure of the previously reported CuCl2·ttda.
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