各向同性混合下一般AMX自旋体系的解析相干传递函数

Oliver Schedletzky, Steffen J. Glaser
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引用次数: 24

摘要

在各向同性混合条件下,给出了由任意耦合常数的三个自旋-12组成的自旋系统的解析相干传递函数和极化传递函数。基于这些传递函数,可以为感兴趣的相关性确定混合时间段的最佳持续时间。解析表达式还证明了各向同性混合极化传递函数在三个耦合自旋-12时不会变为负的。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Analytical Coherence-Transfer Functions for the General AMX Spin System under Isotropic Mixing

Analytical coherence- and polarization-transfer functions are presented for spin systems consisting of three spins-12 with arbitrary coupling constants under isotropic-mixing conditions. Based on these transfer functions, optimal durations for the mixing-time period can be determined for correlations of interest. The analytical expressions also make it possible to prove that isotropic-mixing polarization-transfer functions cannot become negative for three coupled spins-12.

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