三聚氰胺氰脲酸酯对短切玻璃纤维增强聚苯醚/聚苯乙烯/尼龙-6热阻燃性能的影响

P. Hadimani, H. N. Narasimha Murthy, R. Mudbidre, G. Angadi
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引用次数: 1

摘要

本文研究了三聚氰胺氰脲酸酯对在双螺杆共转挤出机中加工的短切玻璃纤维(40 wt.%)增强聚苯醚/聚苯乙烯/尼龙-6 (40/40/20 wt.%)的热阻燃性能的影响。采用注射成型方法制备复合材料。三聚氰胺氰脲酸盐的加入降低了三元合金的有毒气体和有机挥发性化合物的含量、结晶度、结晶温度和熔体温度,但同样的阻燃剂提高了三元合金的玻璃化转变温度和热变形温度。在UL94试验中,当三聚氰胺氰酸盐添加量分别为5%和10%时,阻燃性能达到了V0级和V2级,极限氧指数为35%。三聚氰胺氰脲酸盐的加入提高了三元合金的拉伸模量和断裂伸长率,但降低了三元合金的熔体流动速率和含水率。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Effect of melamine cyanurate on thermal and flame-retardant behaviour of chopped glass fibre reinforced polyphenylene ether/polystyrene/nylon-6
This paper deals with the effect of melamine cyanurate on the thermal and fire retardant behaviour of chopped glass fibre (40 wt.%) reinforced polyphenylene ether/polystyrene/nylon-6 (40/40/20 wt. %) which are processed in a twin screw co-rotating extruder. The composite specimens were fabricated by injection moulding. Addition of melamine cyanurate decreased the amount of toxic gases and organic volatile compounds, crystallinity, crystalline temperature and melt temperature but the same fire-retardant increased glass transition temperature and heat distortion temperature of the ternary alloy. Flame retardancy with V0 and V2 rating along with Limiting Oxygen Index 35% was observed in UL94 test for 5 wt. % and 10 wt. % addition of melamine cyanurate, respectively. Addition of melamine cyanurate increased tensile modulus and elongation at break but decreased the melt flow rate and the moisture content of the ternary alloy.
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