萜烯和萜类化合物:生产生物聚合物的基石

Marta E. G. Mosquera, Gerardo Jiménez, Vanessa Tabernero, Joan Vinueza-Vaca, C. García-Estrada, K. Kosalková, Alberto Sola-Landa, Belén Monje, C. Acosta, Rafael Alonso, Miguel Ángel Valera
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引用次数: 20

摘要

聚合物是我们日常生活中必不可少的材料。增值聚合物的合成主要是由化石燃料衍生的单体进行的。然而,采用基于生物经济的循环经济模式将减少对化石燃料的依赖。在这种情况下,生物精炼厂已经出现,将生物质转化为生物能源并生产高附加值产品,包括可以进一步用作合成生物聚合物和生物塑料的基本材料的分子。在开发具有良好机械、热学和化学性能的聚合物时,实现能够聚合天然单体对应物(如萜烯或萜类)的催化体系仍然是一个挑战。本文介绍了最常见的生物塑料和生物聚合物类型,并重点介绍了萜烯和萜类化合物的聚合,它们是制备生物基聚合物和共聚物的有前途的单体来源。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Terpenes and Terpenoids: Building Blocks to Produce Biopolymers
Polymers are essential materials in our daily life. The synthesis of value-added polymers is mainly performed from fossil fuel-derived monomers. However, the adoption of the circular economy model based on the bioeconomy will reduce the dependence on fossil fuels. In this context, biorefineries have emerged to convert biomass into bioenergy and produce high value-added products, including molecules that can be further used as building blocks for the synthesis of biopolymers and bioplastics. The achievement of catalytic systems able to polymerize the natural monomer counterparts, such as terpenes or terpenoids, is still a challenge in the development of polymers with good mechanical, thermal, and chemical properties. This review describes the most common types of bioplastics and biopolymers and focuses specifically on the polymerization of terpenes and terpenoids, which represent a source of promising monomers to create bio-based polymers and copolymers.
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