四配位铱(I)阳离子和氧摄取的配体依赖性:[Ir(PPh2CH3)4]BF4的晶体结构

Journal of The Chemical Society D: Chemical Communications Pub Date : 1971-01-01 DOI:10.1039/C29710000758

G. Clark, C. Reed, W. R. Roper, B. Skelton, T. Waters

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引用次数: 16

摘要

四配位铱(I)阳离子含有各种配体组合，CO, MeCN, Me2SO, PPh3, PPh2Me和PPh2Et，包括对[Ir(PPh2Me)4]BF4的x射线结构分析:这些阳离子配氧的能力被发现对空间因子敏感。

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Four-co-ordinate iridium(I) cations and the ligand dependence of oxygen uptake: the crystal structure of [Ir(PPh2CH3)4]BF4

Four-co-ordinate iridium(I) cations containing various combinations of the ligands, CO, MeCN, Me2SO, PPh3, PPh2Me, and PPh2Et are described including an X-ray structural analysis of [Ir(PPh2Me)4]BF4: the ability of these cations to co-ordinate oxygen is found to be sensitive to steric factors.

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Journal of The Chemical Society D: Chemical Communications

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