邻苯二甲酸四氢酸酐和亚胺:与烯醇和炔醇进行光化学[2+2]环加成反应的高效伙伴

Journal of The Chemical Society, Chemical Communications Pub Date : 1996-01-01 DOI:10.1039/CC9960000249

K. Booker‐Milburn, J. Cowell, Andrew Sharpe, F. Jiménez

{"title":"邻苯二甲酸四氢酸酐和亚胺:与烯醇和炔醇进行光化学[2+2]环加成反应的高效伙伴","authors":"K. Booker‐Milburn, J. Cowell, Andrew Sharpe, F. Jiménez","doi":"10.1039/CC9960000249","DOIUrl":null,"url":null,"abstract":"Intermolecular photochemical [2 + 2] cycloaddition of a variety of alken- and alkyn-3-ols with 3,4,5,6-tetrahydrophthalic anhydride (THPA) and the related imide 4 gave the corresponding cyclobutanes and cyclobutenes in high yield, after relatively short irradiation times, with stereoselectivities as high as 10:1 for the cyclobutane examples.","PeriodicalId":17282,"journal":{"name":"Journal of The Chemical Society, Chemical Communications","volume":"5 1","pages":"249-251"},"PeriodicalIF":0.0000,"publicationDate":"1996-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"12","resultStr":"{\"title\":\"Tetrahydrophthalic Anhydride and Imide: Remarkably Efficient Partners in Photochemical [2+2] Cycloaddition Reactions With Alkenols and Alkynols\",\"authors\":\"K. Booker‐Milburn, J. Cowell, Andrew Sharpe, F. Jiménez\",\"doi\":\"10.1039/CC9960000249\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Intermolecular photochemical [2 + 2] cycloaddition of a variety of alken- and alkyn-3-ols with 3,4,5,6-tetrahydrophthalic anhydride (THPA) and the related imide 4 gave the corresponding cyclobutanes and cyclobutenes in high yield, after relatively short irradiation times, with stereoselectivities as high as 10:1 for the cyclobutane examples.\",\"PeriodicalId\":17282,\"journal\":{\"name\":\"Journal of The Chemical Society, Chemical Communications\",\"volume\":\"5 1\",\"pages\":\"249-251\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1996-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"12\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Chemical Society, Chemical Communications\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/CC9960000249\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society, Chemical Communications","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/CC9960000249","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}

引用次数: 12

摘要

通过分子间光化学[2 + 2]与3,4,5,6-四氢邻苯二酸酐(THPA)和相关的亚胺4进行环加成反应，得到了相应的环丁烷和环丁烯，收率很高，辐照时间较短，以环丁烷为例，立体选择性高达10:1。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文本刊更多论文

Tetrahydrophthalic Anhydride and Imide: Remarkably Efficient Partners in Photochemical [2+2] Cycloaddition Reactions With Alkenols and Alkynols

Intermolecular photochemical [2 + 2] cycloaddition of a variety of alken- and alkyn-3-ols with 3,4,5,6-tetrahydrophthalic anhydride (THPA) and the related imide 4 gave the corresponding cyclobutanes and cyclobutenes in high yield, after relatively short irradiation times, with stereoselectivities as high as 10:1 for the cyclobutane examples.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Journal of The Chemical Society, Chemical Communications

自引率

0.00%

发文量

审稿时长

2 months