基于酚类和席夫碱的改性聚(酯酰胺)和醇酸树脂的合成,研究其在表面涂层中的生物活性和杀虫活性

Roma G. Elfadel, Hala M. Refat, H. Abdelwahab, Salem S. Salem, M. A. Awad, M. A. Abdel Reheim
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引用次数: 0

摘要

目的研究制备的改性醇酸树脂和聚酯酰胺(PEA)树脂作为表面涂层的抗菌和杀虫剂粘合剂。设计/方法/方法制备了水杨酸二乙醇胺和4-(N, N-二甲胺)苄基谷氨酸,并将其作为PEA和醇酸树脂多元醇和二酸的新来源,通过酸值、FT-IR和1H-NMR进行了验证。通过物理力学性能的测量来确定树脂的涂层性能。研究了合成树脂的生物活性和杀虫活性。结果改性后的PEA和醇酸不仅提高了其物理力学性能和化学性能,而且提高了其生物活性和杀虫活性。结果表明,在树脂结构中引入水杨酸二乙醇胺和4-(N, N-二甲胺)苄基谷氨酸改善了PEA和醇酸树脂的薄膜性能,增强了其抗菌性能。研究局限/意义改性醇酸树脂和PEA有机树脂可以作为生物杀灭粘合剂加入到油漆配方中,用于多种表面应用,特别是那些暴露于多种生物的涂料。基于新合成的改性剂改性的醇酸树脂和PEA树脂在抗菌和杀虫剂涂料的生产和开发中具有重要的潜力,使它们能够发挥限制昆虫传播和微生物感染的作用。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Synthesis of modified poly(ester-amide) and alkyd resins based on phenolic and Schiff base compounds to study their biological and insecticide activity for surface coating applications
Purpose This paper aims to investigate the prepared modified alkyd and poly(ester-amide) (PEA) resins as antimicrobial and insecticide binders for surface coating applications. Design/methodology/approach Salicylic diethanolamine and 4-(N, N-dimethylamino) benzylidene glutamic acid were prepared and used as new sources of polyol and dibasic acid for PEA and alkyd resins, then confirmed by: acid value, FT-IR and 1H-NMR. The coating performance of the resins was determined using measurements of physico-mechanical properties. The biological and insecticide activities of the prepared resins were investigated. Findings The tests carried out revealed that the modified PEA and alkyd enhanced both phyisco-mechanical and chemical properties in addition to the biological and insecticide activities. The results of this paper illustrate that the introduction of salicylic diethanolamine and 4-(N, N-dimethylamino) benzylidene glutamic acid within the resin structure improved the film performance and enhanced the antimicrobial activity performance of PEA and alkyd resins. Research limitations/implications The modified alkyd and PEA organic resins can be used as biocidal binders when incorporated into paint formulations for multiple surface applications, especially those that are exposed to several organisms. Originality/value Modified alkyd and PEA resins based on newly synthesized modifiers have a significant potential to be promising in the production and development of antimicrobial and insecticide paints, allowing them to function to restrict the spread of insects and microbial infection.
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