Neville T. Moxon, Jonathan H. Moffett, Anthony K. Gregson
{"title":"与1,1,1,5,5,5 -六氟戊烷- 2,4 -二酮的二聚二氧键接铁(III)配合物的合成与表征","authors":"Neville T. Moxon, Jonathan H. Moffett, Anthony K. Gregson","doi":"10.1016/0022-1902(81)80601-X","DOIUrl":null,"url":null,"abstract":"<div><p>A series of compounds with the empirical formulae Fe(hfa)<sub>2</sub>OR (Hfha = 1, 1, 1, 5, 5, 5-hexafluoropentan-2, 4-dione, R = CH<sub>3</sub>, C<sub>2</sub>H<sub>5</sub>, sec-C<sub>4</sub>H<sub>9</sub>) and the parent material Fe(hfa)<sub>3</sub> have been prepared and characterized using analytical data, IR and optical spectroscopy, magnetic susceptibility measurements and powder X-ray diffraction. The Fe(hfa)<sub>2</sub>OR adducts are antiferromagnetic dimers with <em>J</em> ∼ 12 cm<sup>−1</sup>. Unusual products have been isolated when ethylene glycol is used as the alcohol.</p></div>","PeriodicalId":16275,"journal":{"name":"Journal of Inorganic and Nuclear Chemistry","volume":"43 11","pages":"Pages 2695-2702"},"PeriodicalIF":0.0000,"publicationDate":"1981-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-1902(81)80601-X","citationCount":"6","resultStr":"{\"title\":\"Synthesis and characterization of some dimeric dialkoxo-bridged Fe(III) complexes with 1, 1, 1, 5, 5, 5-hexafluoropentan-2, 4-dione\",\"authors\":\"Neville T. Moxon, Jonathan H. Moffett, Anthony K. Gregson\",\"doi\":\"10.1016/0022-1902(81)80601-X\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>A series of compounds with the empirical formulae Fe(hfa)<sub>2</sub>OR (Hfha = 1, 1, 1, 5, 5, 5-hexafluoropentan-2, 4-dione, R = CH<sub>3</sub>, C<sub>2</sub>H<sub>5</sub>, sec-C<sub>4</sub>H<sub>9</sub>) and the parent material Fe(hfa)<sub>3</sub> have been prepared and characterized using analytical data, IR and optical spectroscopy, magnetic susceptibility measurements and powder X-ray diffraction. The Fe(hfa)<sub>2</sub>OR adducts are antiferromagnetic dimers with <em>J</em> ∼ 12 cm<sup>−1</sup>. Unusual products have been isolated when ethylene glycol is used as the alcohol.</p></div>\",\"PeriodicalId\":16275,\"journal\":{\"name\":\"Journal of Inorganic and Nuclear Chemistry\",\"volume\":\"43 11\",\"pages\":\"Pages 2695-2702\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1981-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/0022-1902(81)80601-X\",\"citationCount\":\"6\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Inorganic and Nuclear Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/002219028180601X\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Inorganic and Nuclear Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/002219028180601X","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Synthesis and characterization of some dimeric dialkoxo-bridged Fe(III) complexes with 1, 1, 1, 5, 5, 5-hexafluoropentan-2, 4-dione
A series of compounds with the empirical formulae Fe(hfa)2OR (Hfha = 1, 1, 1, 5, 5, 5-hexafluoropentan-2, 4-dione, R = CH3, C2H5, sec-C4H9) and the parent material Fe(hfa)3 have been prepared and characterized using analytical data, IR and optical spectroscopy, magnetic susceptibility measurements and powder X-ray diffraction. The Fe(hfa)2OR adducts are antiferromagnetic dimers with J ∼ 12 cm−1. Unusual products have been isolated when ethylene glycol is used as the alcohol.
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